Nickel phosphide decorated Pt nanocatalyst with enhanced electrocatalytic properties toward common small organic molecule oxidation and hydrogen evolution reaction: A strengthened composite supporting effect

2018 ◽  
Vol 43 (6) ◽  
pp. 3203-3215 ◽  
Author(s):  
Fei Zhang ◽  
Huijie Meng ◽  
Wenjuan Zhang ◽  
Mei Wang ◽  
Jinping Li ◽  
...  
2021 ◽  
Vol 9 ◽  
Author(s):  
Woohyeon Jo ◽  
Dasol Jeong ◽  
Jaebum Jeong ◽  
Taegeon Kim ◽  
Seungyeon Han ◽  
...  

Nickel phosphide (Ni-P) films as a catalytic cathode for the hydrogen evolution reaction (HER) of a water splitting were fabricated by a pulse-reverse electrodeposition technique. The electrochemical behaviors for the electrodeposition of Ni-P were investigated by the characterization of peaks in a cyclic voltammogram. The composition of the electrodeposited Ni-P alloys was controlled by adjusting duty cycles of the pulse-reverse electrodeposition. The HER electrocatalytic properties of the Ni-P electrodeposits with an amorphous phase as a function of phosphorous contents existing in Ni-P were electrochemically characterized by the analysis of overpotentials, Tafel slopes, and electrochemical impedance spectrometry. Additionally, the elemental Ni-embedded crystalline Ni3P was prepared by an annealing process with the amorphous Ni69P31 electrodeposit with high contents of phosphorus. The crystalline structure with Ni inclusions in the matrix of Ni3P was formed by the precipitation of excess Ni. The electrocatalytic properties of crystalline Ni3P with elemental Ni inclusions were also investigated by electrochemical characterization.


2021 ◽  
Vol 9 (5) ◽  
pp. 2754-2763
Author(s):  
Kenya Kani ◽  
Hyunsoo Lim ◽  
Andrew E. Whitten ◽  
Kathleen Wood ◽  
Anya J. E. Yago ◽  
...  

The mesoporous RhNi alloy films are synthesized by controlling the concentration of Rh precursor, applied potentials, and pH via the electrochemical co-deposition method with self-assembled polymeric micelles templates for enhancing electrocatalytic properties.


2008 ◽  
Vol 44 (12) ◽  
pp. 1350-1358 ◽  
Author(s):  
V. V. Kuznetsov ◽  
A. A. Kalinkina ◽  
T. V. Pshenichkina ◽  
V. V. Balabaev

Metals ◽  
2018 ◽  
Vol 8 (5) ◽  
pp. 359 ◽  
Author(s):  
Fan Yang ◽  
Ning Kang ◽  
Jiayun Yan ◽  
Xiuli Wang ◽  
Jun He ◽  
...  

2019 ◽  
Vol 3 (8) ◽  
pp. 2006-2014 ◽  
Author(s):  
Jiawei Xia ◽  
Kapil Dhaka ◽  
Michael Volokh ◽  
Guiming Peng ◽  
Zhen Wu ◽  
...  

Electrocatalytic water-splitting is considered as a highly promising technology for the sustainable production of hydrogen.


2015 ◽  
Vol 3 (4) ◽  
pp. 1656-1665 ◽  
Author(s):  
Yuan Pan ◽  
Yanru Liu ◽  
Jinchong Zhao ◽  
Kang Yang ◽  
Jilei Liang ◽  
...  

Monodispersed nickel phosphide nanocrystals (NCs) with different phases were successfully synthesized. The Ni5P4 NCs, with a solid structure, exhibited higher catalytic activity than the Ni12P5 and Ni2P NCs.


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