A Cu(II) coordination framework constructed by the inorganic layer and a bent dipyridyl ligand: synthesis, structure and magnetic properties

Author(s):  
Yuan Tian ◽  
Yong-Qiang Chen ◽  
Jie Li ◽  
Qiang Gao
2020 ◽  
pp. 174751982092601
Author(s):  
Yong-Jun Bian ◽  
Yuan Tian ◽  
Ai-Hua Zhang ◽  
Yong-Qiang Chen

A new coordination framework {[Mn7(L)4(OH)2(H2O)4(DMA)4]·8H2O·6DMA}n (H3 L = 3,3′,3″-[1,3,5-benzenetriyltris(carbonylimino)]tris(benzoate); DMA = N,N-dimethylacetamide) is synthesized under mixed solvothermal conditions. Structural analysis reveals that this complex possesses a three-dimensional framework with (3,10)- c topology based on different [Mn6] clusters. Moreover, magnetic investigations suggest that intra-cluster Mn(II) ions exhibit antiferromagnetic coupling.


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