Micellization behavior of cetyltrimethylammonium bromide in the absence and presence of sodium polystyrene sulfonate in water and methanol-water mixture: A conductivity approach

2019 ◽  
Vol 292 ◽  
pp. 111352 ◽  
Author(s):  
Ajaya Bhattarai
2020 ◽  
Vol 2020 ◽  
pp. 1-13
Author(s):  
Sujit Kumar Shah ◽  
Ajaya Bhattarai

The micellization behavior of cetyltrimethylammonium bromide (CTAB) in water , 0.1, 0.2, 0.3, and 0.4 volume fractions of methanol at 298.15, 308.15, 318.15, and 323.15 K were investigated by surface tension measurements. The effect of methanol on values of critical micelle concentration (cmc), free energies of micellization ΔGmo, and surface properties viz. maximum surface excess concentration Γmax, area occupied by per surfactant molecule Amin, surface pressure πcmc, solution surface tension γcmc, solvent surface tension (γo), free energies of adsorption ΔGadso, the efficiency of adsorption (pC20), effective Gibbs free energy ΔGeffo, and free energy of surface at equilibrium (Gmin) were investigated using surface tension values. Other parameters such as the packing parameter (P), aggregation number (N), concentration of surfactant in the bulk phase (C20), relation between Amin and πcmc, and correlation of slopes dγ/d log C, γo/γcmc, Γ/Γmax, cmc/C20, ΔGadso/ΔGmo, and cmc/pC20 with the volume fraction of methanol are calculated and discussed in the light of the experiment done.


Chirurgia ◽  
2020 ◽  
Vol 33 (1) ◽  
Author(s):  
Moira Pellegrinelli ◽  
Matteo Marchesi ◽  
Osvaldo Morini ◽  
Marco Lotti

1992 ◽  
Vol 21 (11) ◽  
pp. 1312-1315 ◽  
Author(s):  
Denis R Bélanger ◽  
Michael G Tierney ◽  
Garth Dickinson

2017 ◽  
Vol Volume 11 ◽  
pp. 2663-2673 ◽  
Author(s):  
Vanessa Zann ◽  
John McDermott ◽  
Jeffrey Jacobs ◽  
James Davidson ◽  
Fangling Lin ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document