The first Ni(II) complexes of 5-nitroorotate ligand with the tridentate and bidentate coordination modes. Crystal and molecular structures, vibrational spectra and magnetic properties

Polyhedron ◽  
2013 ◽  
Vol 49 (1) ◽  
pp. 259-268 ◽  
Author(s):  
Katarzyna Helios ◽  
Marek Duczmal ◽  
Adam Pietraszko ◽  
Danuta Michalska
1982 ◽  
Vol 37 (12) ◽  
pp. 1584-1589 ◽  
Author(s):  
U. Ensinger ◽  
W. Schwarz ◽  
A. Schmidt

The crystal and molecular structures of tetraethyl- (1), tetra-η-propyl- (2) and tetra-nbutylammonium tetrachloroantimonate(III) (3) were determined by X-ray analysis. There are discrete Sb4Cl164- (1) and Sb2Cl82- (2 and 3) anions. The Sb-Cl bond lengths vary in the range between 234 and 326 pm, and are explained as in a three centre-four electron situation. The vibrational spectra of the anions are briefly discussed


2018 ◽  
Vol 42 (19) ◽  
pp. 15705-15713 ◽  
Author(s):  
Ülo Kersen ◽  
Andrzej Wojtczak ◽  
Alina Bienko ◽  
Julia Jezierska

The crystal and molecular structures and magnetic properties of two new complexes (HMepy)2[CuCl4]·2H2O, 2, and (H2Me2ppz)[CuCl4], 3, formed by tetrachlorocuprate(ii) anions and organic heterocyclic cations, have been determined by the analysis of their X-ray diffraction data, magnetic susceptibility behaviour and EPR spectral parameters.


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