Rare nuclearities, new structural motifs, and slow magnetization relaxation phenomena in manganese cluster chemistry: A Mn15Na2 cage from the use of triethanolamine/pivalate/azide “blend”

The formation and isomerisation of nido-[C2B10H12]2− species is investigated through DFT calculations, which reveal novel basket and inverted nido intermediates and unusual inverconversion pathways, including basket collapse and pivoting triangles and diamonds.

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Unusual Structural Types in Manganese Cluster Chemistry from the Use ofN,N,N‘,N‘-Tetrakis(2-hydroxyethyl)ethylenediamine: Mn8, Mn12, and Mn20Clusters

Inorganic Chemistry ◽

10.1021/ic701971d ◽

2008 ◽

Vol 47 (2) ◽

pp. 621-631 ◽

Cited By ~ 36

Author(s):

Rashmi Bagai ◽

Khalil A. Abboud ◽

George Christou

Keyword(s):

Manganese Cluster ◽

Cluster Chemistry ◽

Structural Types

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New structural topologies in 4f-metal cluster chemistry from vertex-sharing butterfly units: {LnIII7} complexes exhibiting slow magnetization relaxation and ligand-centred emissions

RSC Advances ◽

10.1039/c5ra20454b ◽

2015 ◽

Vol 5 (112) ◽

pp. 92534-92538 ◽

Cited By ~ 15

Author(s):

Eleni C. Mazarakioti ◽

Luís Cunha-Silva ◽

Vlasoula Bekiari ◽

Albert Escuer ◽

Theocharis C. Stamatatos

Keyword(s):

Metal Cluster ◽

Magnetization Relaxation ◽

Cluster Chemistry ◽

Metal Chemistry ◽

Vertex Sharing

The employment of N-salicylidene-o-aminophenol in 4f-metal chemistry has led to a family of {Ln7} clusters with a new core topology, SMM behavior and ligand-centered emissions.

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New structural motifs in Mn cluster chemistry from the ketone/gem-diol and bis(gem-diol) forms of 2,6-di-(2-pyridylcarbonyl)pyridine: {MnII4MnIII2} and {MnII4MnIII6} complexes

RSC Advances ◽

10.1039/c6ra22953k ◽

2016 ◽

Vol 6 (107) ◽

pp. 105969-105979 ◽

Cited By ~ 1

Author(s):

Dimosthenis P. Giannopoulos ◽

Luís Cunha-Silva ◽

Rafael Ballesteros-Garrido ◽

Rafael Ballesteros ◽

Belén Abarca ◽

...

Keyword(s):

Structural Motifs ◽

Cluster Chemistry ◽

Mn Cluster

The ketone/gem-diol (L1H2) and bis(gem-diol) (L2H4) forms of the ligand 2,6-di-(2-pyridylcarbonyl)pyridine in Mn cluster chemistry have afforded the new complexes [MnII4MnIII2(N3)6Cl4(L1)2(DMF)4] and [MnII4MnIII6O2(N3)12(L1)2(L2H)2(DMF)6].

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Azide Groups in Higher Oxidation State Manganese Cluster Chemistry: From Structural Aesthetics to Single-Molecule Magnets

Inorganic Chemistry ◽

10.1021/ic801217j ◽

2009 ◽

Vol 48 (8) ◽

pp. 3308-3322 ◽

Cited By ~ 122

Author(s):

Theocharis C. Stamatatos ◽

George Christou

Keyword(s):

Oxidation State ◽

Single Molecule ◽

Manganese Cluster ◽

Single Molecule Magnets ◽

Cluster Chemistry

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A new twist on an old ligand: a [Mn16] double square wheel and a [Mn10] contorted wheel

Inorganic Chemistry Frontiers ◽

10.1039/d0qi01495h ◽

2021 ◽

Vol 8 (7) ◽

pp. 1804-1809 ◽

Cited By ~ 1

Author(s):

Thomais G. Tziotzi ◽

Marco Coletta ◽

Mark Gray ◽

Cameron L. Campbell ◽

Scott J. Dalgarno ◽

...

Keyword(s):

Manganese Cluster ◽

Cluster Chemistry

The use of 1,3,5-tri(2-hydroxyethyl)-1,3,5-triazacyclohexane (LH3) in manganese cluster chemistry leads to the synthesis of a {Mn16} double square wheel and a {Mn10} contorted wheel.

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