Synthetic strategies, structures and properties of di and polynuclear cobalt complexes with H2salen type Schiff bases and their reduced analogues

Polyhedron ◽  
2021 ◽  
pp. 115511
Author(s):  
Tamashi Ghosh Dastidar ◽  
Shouvik Chattopadhyay
2018 ◽  
Vol 42 (6) ◽  
pp. 4646-4652 ◽  
Author(s):  
Hua Zhang ◽  
Junyang Xing ◽  
Yanhong Dong ◽  
Shangqing Xie ◽  
Shishuai Ren ◽  
...  

The sp2 C–H bond activation of the HCN moiety in diphenylphosphino benzalimines was realized using CoMe(PMe3)4 with the elimination of methane.


Polyhedron ◽  
1998 ◽  
Vol 17 (22) ◽  
pp. 3859-3874 ◽  
Author(s):  
Hitoshi Torayama ◽  
Hideyuki Asada ◽  
Manabu Fujiwara ◽  
Takayuki Matsushita

2014 ◽  
Vol 2014 ◽  
pp. 1-12 ◽  
Author(s):  
Selma Bal ◽  
Sedat Salih Bal

Carbazoles containing two new Schiff bases (Z,Z)-N,N′-bis[(9-ethyl-9H-carbazole-3-yl)methylene]propane-1,3 diamine (L1) and (Z,Z)-N,N′-bis[(9-ethyl-9H-carbazole-3-yl)methylene]-2,2-dimethylpropane-1,3-diamine (L2) and their Co(II) and Mn(II) complexes were synthesized and characterized using various spectroscopic methods and thermal analysis, which gave high thermal stability results for the ligands and their cobalt complexes. The title compounds were examined for their antimicrobial and antifungal activities, which resulted in high activity values for the ligands and their manganese complexes. Oxidation reactions carried out on styrene and cyclohexene revealed that the complex compounds were the most effective catalysts for styrene oxidation, giving good selectivities than those of cyclohexene oxidation. Electronic features of the synthesized compounds were also reported within this work.


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