Oxidative sulfamidation of vinyl silanes: A route to diverse silylated N-Heterocycles

Tetrahedron ◽  
2019 ◽  
Vol 75 (33) ◽  
pp. 4531-4541 ◽  
Author(s):  
Vera V. Astakhova ◽  
Bagrat A. Shainyan ◽  
Mikhail Yu. Moskalik ◽  
Irina V. Sterkhova
Keyword(s):  
Vinyl Silanes

The synthesis and polymerization of vinyl silanes possessing two functional groups on the silicon atom

1977 ◽  
Vol 19 (4) ◽  
pp. 868-874 ◽  
Author(s):  
K.A. Andrianov ◽  
N.V. Delazari ◽  
N.A. Yemel'kina ◽  
Z.V. Pechorkina ◽  
L.A. Leites
Keyword(s):  
Functional Groups ◽  
Silicon Atom ◽  
Vinyl Silanes

scholarly journals Non-Selective Dimerization of Vinyl Silanes by the Putative (Phenanthroline)PdMe Cation to 1,4-Bis(trialkoxysilyl)butenes

Inorganics ◽  
2018 ◽  
Vol 6 (4) ◽  
pp. 102
Author(s):  
Sandun Perera ◽  
Michael Findlater
Keyword(s):  
Nmr Spectroscopy ◽  
Palladium Complex ◽  
Organic Products ◽  
Vinyl Silanes ◽  
In Situ Nmr Spectroscopy ◽  
In Situ Nmr ◽  
Moderate Yield

Activation of the dialkylpalladium complex (phen)Pd(CH3)2 (phen = 1,10-phenanthroline) with B(C6F5)3 affords a competent catalyst for the dimerization of vinyl silanes. All organic products of the catalytic dimerization of trialkoxyvinylsilanes were characterized by in situ NMR spectroscopy and GC–MS. The putative palladium cation was characterized by NMR spectroscopy. Upon activation, the palladium complex generated products in moderate yield (60–70%) and selectivity (~60:40, dimer:disproportionation products).

Palladium-catalyzed olefination of aryl/alkyl halides with trimethylsilyldiazomethane via carbene migratory insertion

2018 ◽  
Vol 54 (92) ◽  
pp. 12994-12997 ◽  
Author(s):  
Qiu-Chao Mu ◽  
Xing-Ben Wang ◽  
Fei Ye ◽  
Yu-Li Sun ◽  
Xing-Feng Bai ◽  
...  
Keyword(s):  
Alkyl Halides ◽  
One Pot ◽  
Migratory Insertion ◽  
Palladium Catalyzed ◽  
Vinyl Silanes

One-pot formation of (E)-vinyl silanes and (E)-silyl-substituted α, β-unsaturated amides could be completed easily via palladium carbene migratory insertion in good yields and high chemoselectivity.

Tandem photochemical or thermal [1,5]-H, thermal [1,5]-Si migrations of vinyl silanes

1993 ◽  
Vol 34 (51) ◽  
pp. 8217-8220 ◽  
Author(s):  
Michael C. Pirrung ◽  
Yong Rok Lee
Keyword(s):  
Vinyl Silanes

The reaction of chloroalkyl(vinyl)silanes with N,N-dichloro sulfonamides

2020 ◽  
Vol 30 (6) ◽  
pp. 794-795
Author(s):  
Irina V. Ushakova ◽  
Bagrat A. Shainyan
Keyword(s):  
Vinyl Silanes

(2+1) Cycloaddition of chloro(phenylthio)carbene to vinyl silanes. A facile synthesis of highly functionalized cyclopropanes

Tetrahedron ◽  
1989 ◽  
Vol 45 (10) ◽  
pp. 3163-3170 ◽  
Author(s):  
Ernst Schaumann ◽  
Carsten Friese ◽  
Gunadi Adiwidjaja
Keyword(s):  
Facile Synthesis ◽  
Vinyl Silanes

ChemInform Abstract: ALIPHATIC FRIEDEL-CRAFTS ACYLATION OF VINYL SILANES

1975 ◽  
Vol 6 (44) ◽  
pp. no-no
Author(s):  
I. FLEMING ◽  
A. PEARCE
Keyword(s):  
Vinyl Silanes

Fused Silacarbacycles Containing a Silole Unit: 1,2-Hydroboration and 1,1-Organoboration of Alkynyl(vinyl)silanes

2010 ◽  
Vol 2010 (15) ◽  
pp. 2276-2282 ◽  
Author(s):  
Bernd Wrackmeyer ◽  
Oleg L. Tok ◽  
Elena V. Klimkina ◽  
Wolfgang Milius
Keyword(s):  
Vinyl Silanes

Nitrone cycloadditions with vinyl silanes: the total synthesis of deoxysugars.

1984 ◽  
Vol 25 (47) ◽  
pp. 5355-5358 ◽  
Author(s):  
Philip DeShong ◽  
Joseph M. Leginus
Keyword(s):  
Total Synthesis ◽  
Vinyl Silanes
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