Proton magnetic resonance spectra of metal ammine complexes. IX. Stereoelectronic effect in the activation of α-hydrogen atoms of coordinated amino acids

1978 ◽  
Vol 31 ◽  
pp. L473-L474 ◽  
Author(s):  
Ushio Sakaguchi ◽  
Hayami Yoneda ◽  
Yukiyoshi Morimoto
1967 ◽  
Vol 20 (8) ◽  
pp. 1663 ◽  
Author(s):  
JFK Wilshire

2-Fluoro-5-nitrobenzonitrile, an analogue of 1-fluoro-2,4- dinitrobenzene, in which the 2-nitro group has been replaced by a cyano group, has been prepared and made to react with several amines, amino acids, and NH-heteroaromatic compounds. The proton magnetic resonance spectra of some of the resultant N-(2-cyano-4-nitrophenyl) derivatives were compared with the spectra of the corresponding N-(2,4- dinitrophenyl) derivatives and furnish further evidence that the ortho nitro group of the latter derivatives is rotated out of the plane of the aromatic nucleus.


1965 ◽  
Vol 4 (7) ◽  
pp. 1064-1066 ◽  
Author(s):  
William L. Jolly ◽  
Arlo D. Harris ◽  
Thomas S. Briggs

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