A mechanistic study of thermal C-H reductive elimination from a six-coordinate d6 iridium complex

1998 ◽  
Vol 270 (1-2) ◽  
pp. 537-542 ◽  
Author(s):  
Glen P. Rosini ◽  
Kun Wang ◽  
Bhushan Patel ◽  
Alan S. Goldman
Keyword(s):  
Reductive Elimination ◽  
Mechanistic Study ◽  
Iridium Complex

A computational mechanistic study of Pd(ii)-catalyzed γ-C(sp3)–H olefination/cyclization of amines: the roles of bicarbonate and ligand effect

2018 ◽  
Vol 47 (14) ◽  
pp. 4893-4901 ◽  
Author(s):  
Jian-Biao Liu ◽  
Ying-Ying Tian ◽  
Xin Zhang ◽  
Lu-Lin Wang ◽  
De-Zhan Chen
Keyword(s):  
Reductive Elimination ◽  
Mechanistic Study ◽  
Ligand Effect

The bicarbonate aids the C–H activation and abstracts the β-proton in the reductive eliminationviaa PCET mechanism.

Ruthenium-catalyzed deoxygenative hydroboration of carboxylic acids: a DFT mechanistic study

2019 ◽  
Vol 43 (29) ◽  
pp. 11493-11496
Author(s):  
Qianyue Wang ◽  
Longfei Li ◽  
Pengjie Li ◽  
Xin Yue ◽  
Zuoyin Yang ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Reductive Elimination ◽  
Dft Study ◽  
Mechanistic Study

A DFT study indicates that the second HBpin coordination with the Ru center could facilitate the reductive elimination step.

Dimerization of Alkynes Promoted by a Pincer-Ligated Iridium Complex. C−C Reductive Elimination Inhibited by Steric Crowding

2007 ◽  
Vol 129 (4) ◽  
pp. 853-866 ◽  
Author(s):  
Rajshekhar Ghosh ◽  
Xiawei Zhang ◽  
Patrick Achord ◽  
Thomas J. Emge ◽  
Karsten Krogh-Jespersen ◽  
...  
Keyword(s):  
Reductive Elimination ◽  
Iridium Complex ◽  
Steric Crowding ◽  
Dimerization Of Alkynes
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