Synthesis of optically active γ-trimethylsilyl-β,γ-epoxy tertiary alcohols by the diastereoselective addition reaction of β-trimethylsilyl-α,β-epoxyketones with Grignard reagents

1991 ◽  
Vol 32 (41) ◽  
pp. 5789-5792 ◽  
Author(s):  
Sentaro Okamoto ◽  
Hiromi Tsujiyama ◽  
Toshiharu Yoshino ◽  
Fumie Sato
Keyword(s):  
Addition Reaction ◽  
Optically Active ◽  
Grignard Reagents ◽  
Tertiary Alcohols ◽  
Diastereoselective Addition

ChemInform Abstract: Diastereoselective Addition Reaction of Optically Active Alcohols and Amines to λ3-Iminophosphines.

ChemInform ◽  
1989 ◽  
Vol 20 (25) ◽  
Author(s):  
L. N. MARKOVSKII ◽  
V. D. ROMANENKO ◽  
A. V. RUBAN ◽  
A. B. DRAPAILO ◽  
M. MIKOLAICHIK ◽  
...  
Keyword(s):  
Addition Reaction ◽  
Optically Active ◽  
Diastereoselective Addition

Stereodivergent synthesis of optically active tertiary alcohols via addition reaction of chiral 2-acyl oxazolidine with organometallics

1991 ◽  
Vol 32 (25) ◽  
pp. 2919-2922 ◽  
Author(s):  
Yutaka Ukaji ◽  
Kouji Yamamoto ◽  
Masashi Fukui ◽  
Tamotsu Fujisawa
Keyword(s):  
Addition Reaction ◽  
Optically Active ◽  
Tertiary Alcohols

Diastereoselective Synthesis of Morpholine Derivatives from Grignard Reagents and N-Sulfinyl Imines

Synlett ◽  
2021 ◽  
Author(s):  
Eric P. A. Talbot ◽  
Joseph M. Bateman ◽  
Diana Chan ◽  
Mustafa Moroglu ◽  
Benjamin Rahemtulla
Keyword(s):  
Grignard Reagent ◽  
Stereoselective Synthesis ◽  
Grignard Reagents ◽  
Diastereoselective Synthesis ◽  
Step Process ◽  
Diastereoselective Addition ◽  
Morpholine Derivatives

The stereoselective synthesis of C3-substituted morpholine derivatives has been achieved through a two-step process involving diastereoselective addition of a Grignard reagent to a sulfinyl imine, followed by cyclization.

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