On the mechanism of the photochemical rearrangement of 3-phenyl substituted cyclopropenes to indenes

1977 ◽  
Vol 18 (33) ◽  
pp. 2847-2850 ◽  
Author(s):  
Albert Padwa ◽  
Roman Loza ◽  
Daniel Getman
Keyword(s):  
Photochemical Rearrangement

Photochemical Rearrangement of Oxaziridines and Nitrones in the Hexahydroindole Series: A Convenient Synthetic Route to 1-Azabicyclo[5.2.0]nonan-2-ones as Novel RGD Mimetics

2001 ◽  
Vol 3 (20) ◽  
pp. 3067-3070 ◽  
Author(s):  
Erika Bourguet ◽  
Jean-Louis Baneres ◽  
Jean-Pierre Girard ◽  
Joseph Parello ◽  
Jean-Pierre Vidal ◽  
...  
Keyword(s):  
Synthetic Route ◽  
Photochemical Rearrangement

PHOTOCHEMICAL REARRANGEMENT OF 3-PHENYLATED 2(3H)-OXEPINONES IN ACIDIC MEDIA. FORMATION OF 5-STYRYL-2(5H)-FURANONES

1979 ◽  
Vol 8 (10) ◽  
pp. 1291-1294 ◽  
Author(s):  
Nobuto Hoshi ◽  
Hisahiro Hagiwara ◽  
Hisashi Uda
Keyword(s):  
Acidic Media ◽  
Photochemical Rearrangement

Photochemical Rearrangement ofN-Chlorolactams: A Route toN-Heterocycles through Concerted Ring Contraction

2010 ◽  
Vol 75 (8) ◽  
pp. 2610-2618 ◽  
Author(s):  
Dana K. Winter ◽  
Alexandre Drouin ◽  
Jean Lessard ◽  
Claude Spino
Keyword(s):  
Ring Contraction ◽  
Photochemical Rearrangement

An unusual abnormal Wolff rearrangement

2003 ◽  
Vol 81 (6) ◽  
pp. 517-524 ◽  
Author(s):  
Howard E Zimmerman ◽  
Pengfei Wang
Keyword(s):  
Reaction Mechanism ◽  
Ab Initio ◽  
Transition Structure ◽  
Wolff Rearrangement ◽  
Photochemical Rearrangement ◽  
Bicyclic Structure

An unusual example of the abnormal Wolff rearrangement was studied. The bicyclic structure of the reactant and intermediates precluded some mechanistic possibilities of this unusual Abnormal Wolff Rearrangement. The study involved the photochemical rearrangement of diazodehydronorbornone bearing phenyl and 2-pyridyl groups at C-7. A number of examples of interesting stereoselectivity were encountered. The mechanism was investigated by use of ab initio QST type computations which located a unique transition structure species accounting for the reaction mechanism.Key words: abnormal-Wolff, carbene, rearrangement, QM computations, reaction mechanism.

ChemInform Abstract: Efficient Synthesis of Polysubstituted Isochromanones via a Novel Photochemical Rearrangement.

ChemInform ◽  
2012 ◽  
Vol 43 (6) ◽  
pp. no-no
Author(s):  
Wujiong Xia ◽  
Yutian Shao ◽  
Weijun Gui ◽  
Chao Yang
Keyword(s):  
Efficient Synthesis ◽  
Photochemical Rearrangement

Mechanistic studies of the photochemical rearrangement of 1-oxolongipin-2-ene derivatives

Tetrahedron ◽  
2002 ◽  
Vol 58 (12) ◽  
pp. 2331-2338 ◽  
Author(s):  
Myriam Meléndez-Rodrı́guez ◽  
Carlos M Cerda-Garcı́a-Rojas ◽  
César A.N Catalán ◽  
Pedro Joseph-Nathan
Keyword(s):  
Mechanistic Studies ◽  
Photochemical Rearrangement

scholarly journals Photochemical Rearrangement of Ethyl Aryl Carbonates

1969 ◽  
Vol 72 (1) ◽  
pp. 224-229
Author(s):  
Chyongjin PAC ◽  
Shigeru TSUTSUMI ◽  
Hiroshi SAKURAI
Keyword(s):  
Photochemical Rearrangement

Novel and efficient photochemical rearrangement of 1,3-thiazine derivatives

1981 ◽  
pp. 608 ◽  
Author(s):  
Peter B. Hitchcock ◽  
Richard W. McCabe ◽  
Douglas W. Young ◽  
Gareth M. Davies
Keyword(s):  
Photochemical Rearrangement
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