Immobilization of polymer-stabilized metal colloids by a modified coordination capture: preparation of supported metal colloids with singular catalytic properties

1999 ◽  
Vol 142 (2) ◽  
pp. 201-211 ◽  
Author(s):  
Weiyong Yu ◽  
Manhong Liu ◽  
Hanfan Liu ◽  
Xiaohua An ◽  
Zhijie Liu ◽  
...  
2019 ◽  
Vol 6 (11) ◽  
pp. 3041-3056 ◽  
Author(s):  
Jingkun Lu ◽  
Peipei He ◽  
Jingyang Niu ◽  
Jingping Wang

This review aims to give an overview of the POM-supported metal carbonyl complexes obtained so far, focusing on their structural diversity and potential photochemical and catalytic properties.


2006 ◽  
Vol 348 (12-13) ◽  
pp. 1734-1742 ◽  
Author(s):  
Boyapati M. Choudary ◽  
Moumita Roy ◽  
Sarabindu Roy ◽  
M. Lakshmi Kantam ◽  
Bojja Sreedhar ◽  
...  

2018 ◽  
Vol 208 ◽  
pp. 443-454 ◽  
Author(s):  
Scott M. Rogers ◽  
C. Richard A. Catlow ◽  
Diego Gianolio ◽  
Peter P. Wells ◽  
Nikolaos Dimitratos

Nanoparticle property control, and excellent catalytic capabilities, has been demonstrated using Pd/TiO2 prepared by sol-immobilisation with solvent and temperature control.


2019 ◽  
Author(s):  
Arthur Bonfá Fernandes ◽  
Mariia V. Pavliuk ◽  
Cristina Paun ◽  
Alexandrina C. Carvalho ◽  
Cassiana S. Nomura ◽  
...  

Metal nanoparticles have been widely exploited in catalysis, but their full impact on the environment and human health is still under debate. Here we describe the one-step fabrication of polymer microbead-supported metal and metal oxide nanoparticles and their application as recoverable nanocatalysts for reactions under batch and flow conditions. Au, Ag and Fe<sub>3</sub>O<sub>4</sub> nanoparticles were prepared directly at the surface of benzylamine-coated spherical polymer beads in water by using low energy microwave radiation. The morphology and size of the nanoparticles, and therefore their catalytic properties, were tuned by modifying the bead surface using betalamic acid, an antioxidant from plant origin. The catalytic performance and recovery of these environmentally friendly nanocatalysts was demonstrated towards model redox chemical transformations. We anticipate the results reported herein can provide important insights into the controlled and facile synthesis of microparticle supported nanocatalysts under mild conditions.


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