Pd-Catalyzed Three-Component Reaction of 3-(Pinacolatoboryl)ally Acetates, Aldehydes, and Organoboranes: A New Entry to Stereoselective Synthesis of (Z)-anti-Homoallylic Alcohols

2015 ◽  
Vol 17 (11) ◽  
pp. 2824-2827 ◽  
Author(s):  
Yoshikazu Horino ◽  
Ataru Aimono ◽  
Hitoshi Abe
Keyword(s):  
Stereoselective Synthesis ◽  
Homoallylic Alcohols ◽  
Three Component Reaction ◽  
New Entry

Controllable Stereoselective Synthesis of (Z)- and (E)-Homoallylic Alcohols Using a Palladium-Catalyzed Three-Component Reaction

2017 ◽  
Vol 19 (21) ◽  
pp. 5968-5971 ◽  
Author(s):  
Yoshikazu Horino ◽  
Miki Sugata ◽  
Itaru Mutsuura ◽  
Keisuke Tomohara ◽  
Hitoshi Abe
Keyword(s):  
Stereoselective Synthesis ◽  
Homoallylic Alcohols ◽  
Three Component Reaction ◽  
Palladium Catalyzed

An efficient one-pot stereoselective synthesis of 2,6-disubstituted 4-thiocyanatotetrahydropyrans

2021 ◽  
Vol 08 ◽  
Author(s):  
Chithaluri Sudhakar ◽  
Pochamoni Ramudu
Keyword(s):  
Room Temperature ◽  
Stereoselective Synthesis ◽  
One Pot ◽  
Three Component Reaction

: An efficient stereoselective synthesis of 2,6-disubstituted-4-thiocyanatotetrahydropyrans has been developed through a one pot three-component reaction of aldehydes, trimethyl allylsilane and NH4SCN in the presence of BF3.Et2O at room temperature. The products are formed rapidly (10-30 min) in excellent yields (78-98%).

Regio- and Stereoselective Synthesis of Homoallylic Alcohols Based on the Use of (3-Chloroprop-1-en-1-yl)boronates.

ChemInform ◽  
2003 ◽  
Vol 34 (1) ◽  
pp. no-no
Author(s):  
Marco Lombardo ◽  
Stefano Morganti ◽  
Massimo Tozzi ◽  
Claudio Trombini
Keyword(s):  
Stereoselective Synthesis ◽  
Homoallylic Alcohols

Catalytic carboboration of dienylboronate for stereoselective synthesis of (E)-γ′,δ-bisboryl-anti-homoallylic alcohols

2019 ◽  
Vol 55 (75) ◽  
pp. 11199-11202 ◽  
Author(s):  
Shang Gao ◽  
Ming Chen
Keyword(s):  
Stereoselective Synthesis ◽  
Homoallylic Alcohols

A Cu-catalyzed stereoselective carboboration of dienylboronate for the synthesis of (E)-γ′,δ-bisboryl-anti-homoallylic alcohols was developed.

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