Cooperative Iron–Oxygen–Copper Catalysis in the Reduction of Benzaldehyde under Water-Gas Shift Reaction Conditions

ACS Catalysis ◽  
2016 ◽  
Vol 6 (11) ◽  
pp. 7855-7864 ◽  
Author(s):  
Arundhoti Chakraborty ◽  
R. Garrison Kinney ◽  
Jeanette A. Krause ◽  
Hairong Guan
2010 ◽  
Vol 157 (3) ◽  
pp. B383 ◽  
Author(s):  
Jianlin Li ◽  
Heesung Yoon ◽  
Tak-keun Oh ◽  
Eric D. Wachsman

1991 ◽  
Vol 10 (7) ◽  
pp. 2493-2498 ◽  
Author(s):  
Takashi. Joh ◽  
Kazuo. Doyama ◽  
Kiyotaka. Onitsuka ◽  
Tomoo. Shiohara ◽  
Shigetoshi. Takahashi

Synthesis ◽  
2018 ◽  
Vol 50 (22) ◽  
pp. 4369-4376 ◽  
Author(s):  
Matthias Beller ◽  
Pavel Ryabchuk ◽  
Kathrin Junge

Reduction of various nitroarenes in the presence of heterogeneous iron oxide-based catalyst Fe2O3/NGr@C under water-gas shift reaction (WGSR) conditions has been demonstrated. The catalytic material is prepared in a straightforward manner via deposition/pyrolysis of iron-phenanthroline complex on carbon support. It shows high chemoselectivity towards the reduction of nitroarenes in the presence of other reducible and/or poisoning-capable functional groups. Hydrogenation is achieved using CO/H2O as a hydrogen source. Furthermore, it is demonstrated that the presence of triethylamine additive has a significant positive effect on the rate of reduction.


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