Structures, Photoluminescence, and Photocatalytic Properties of Six New Metal−Organic Frameworks Based on Aromatic Polycarboxylate Acids and Rigid Imidazole-Based Synthons
Solvent-assisted linker exchange (SALE) was performed on two pillared metal–organic frameworks (MOFs), [Zn2(oba)2(4-bpdb)]n·(DMF)2 (TMU-4) and [Zn(oba)(4-bpmb)0.5]n·(DMF)1.5 (TMU-6), to tune their photocatalytic properties.
Two new 3D Ln-based complexes showing (6,8)-connected topology were synthesized and the photocatalytic activity of the Sm(iii)-based MOF towards the degradation of methyl violet (MV) in water explored.
Metal node substitution in metal organic frameworks is an efficient strategy to enhance photocatalytic properties. Herein, bimetallic CeZr5-MOFs UiO-66 photocatalysts were successfully synthesized by partial replacing Zr with Ce for...