Rotational spectrum and structure of a hydrogen-bonded dimer of phosphine with hydrogen bromide

1983 ◽  
Vol 87 (12) ◽  
pp. 2085-2090 ◽  
Author(s):  
L. C. Willoughby ◽  
A. C. Legon

The microwave rotational spectrum of the hydrogen-bonded heterodimer CH 3 CN • • • HF has been identified and shown to be characteristic of a symmetric top. A detailed analysis of several rotational transitions for a variety of isotopic species gives the spectroscopic constants summarized in the following table: Rotational constants/MHz, vibration-rotation constants/MHz and vibrational separations/cm -1 of CH 3 CN • • • HF





Proc. R. Soc. Lond. A 401, 327-347 (1985) Spectroscopic investigations of hydrogen bonding interactions in the gas phase. X. Properties of the hydrogen-bonded heterodimer HCN⋯HF determined from hyperfine coupling and centrifugal distortion effects in its ground-state rotational spectrum By A. C. Legon, D. J. Millen and L. C. Willoughby On p. 327, at the end of the abstract, for 0.14 Å read 0.014 Å. On p. 343, line 7, for 0.025 Å read 0.014 Å. On p. 344, line 27, for 25.4° read 21.7°; line 33, for 6.6° read 2.9°. On p. 347, line 12, for 0.025 Å read 0.014 Å.



1995 ◽  
Vol 232 (3) ◽  
pp. 187-191 ◽  
Author(s):  
Z. Kisiel ◽  
P.W. Fowler ◽  
A.C. Legon


1985 ◽  
Vol 117 (6) ◽  
pp. 543-549 ◽  
Author(s):  
G. Cazzoli ◽  
P.G. Favero ◽  
D.G. Lister ◽  
A.C. Legon ◽  
D.J. Millen ◽  
...  


1986 ◽  
Vol 145 (3-4) ◽  
pp. 261-276 ◽  
Author(s):  
A.I. Jaman ◽  
A.C. Legon


Sign in / Sign up

Export Citation Format

Share Document