Palladium-catalyzed carbonyl allylation by allylic alcohols with stannous chloride

1992 ◽  
Vol 114 (7) ◽  
pp. 2577-2586 ◽  
Author(s):  
Jun P. Takahara ◽  
Yoshiro Masuyama ◽  
Yasuhiko Kurusu
Keyword(s):  
Stannous Chloride ◽  
Allylic Alcohols ◽  
Palladium Catalyzed ◽  
Carbonyl Allylation

Allylic alcohols as synthons of allylic carbanions. Palladium-catalyzed carbonyl allylation by allylic alcohols with tin dichloride

1988 ◽  
Vol 110 (13) ◽  
pp. 4473-4474 ◽  
Author(s):  
Yoshiro. Masuyama ◽  
Jun P. Takahara ◽  
Yasuhiko. Kurusu
Keyword(s):  
Allylic Alcohols ◽  
Palladium Catalyzed ◽  
Carbonyl Allylation

ChemInform Abstract: Palladium-Catalyzed Carbonyl Allylation of Diketo Compounds by Allylic Alcohols with SnCl2.

ChemInform ◽  
1990 ◽  
Vol 21 (27) ◽  
Author(s):  
Y. MASUYAMA ◽  
T. TSUNODA ◽  
Y. KURUSU
Keyword(s):  
Allylic Alcohols ◽  
Palladium Catalyzed ◽  
Carbonyl Allylation

A solid-phase version of the palladium-catalyzed carbonyl allylation by allylic alcohols with SnCl2

2001 ◽  
Vol 42 (19) ◽  
pp. 3299-3302 ◽  
Author(s):  
Lydia Carde ◽  
Amadeu Llebaria ◽  
Antonio Delgado
Keyword(s):  
Solid Phase ◽  
Allylic Alcohols ◽  
Palladium Catalyzed ◽  
Carbonyl Allylation

ChemInform Abstract: Palladium-Catalyzed Carbonyl Allylation by Allylic Alcohols with SnCl2. A Solvation-Controlled Diastereoselection.

ChemInform ◽  
1990 ◽  
Vol 21 (6) ◽  
Author(s):  
Y. MASUYAMA ◽  
J. P. TAKAHARA ◽  
Y. KURUSU
Keyword(s):  
Allylic Alcohols ◽  
Palladium Catalyzed ◽  
Carbonyl Allylation

Palladium-Catalyzed Carbonyl Allylation of Diketo Compounds by Allylic Alcohols with SnCl2

1989 ◽  
Vol 18 (9) ◽  
pp. 1647-1650 ◽  
Author(s):  
Yoshiro Masuyama ◽  
Tomoyoshi Tsunoda ◽  
Yasuhiko Kurusu
Keyword(s):  
Allylic Alcohols ◽  
Palladium Catalyzed ◽  
Carbonyl Allylation

ChemInform Abstract: Allylic Alcohols as Synthons of Allylic Carbanions. Palladium-Catalyzed Carbonyl Allylation by Allylic Alcohols with SnCl2.

ChemInform ◽  
1988 ◽  
Vol 19 (42) ◽  
Author(s):  
Y. MASUYAMA ◽  
J. P. TAKAHARA ◽  
Y. KURUSU
Keyword(s):  
Allylic Alcohols ◽  
Palladium Catalyzed ◽  
Carbonyl Allylation

Palladium-catalyzed carbonyl allylation by allylic alcohols with SnCl2. A solvation-controlled diastereoselection

1989 ◽  
Vol 30 (26) ◽  
pp. 3437-3440 ◽  
Author(s):  
Yoshiro Masuyama ◽  
Jun P. Takahara ◽  
Yasuhiko Kurusu
Keyword(s):  
Allylic Alcohols ◽  
Palladium Catalyzed ◽  
Carbonyl Allylation

scholarly journals Palladium-Catalyzed Carbonyl Allylation Reactions Using Tin Chloride: A Mini-Review

KIMIKA ◽  
2018 ◽  
Vol 29 (1) ◽  
pp. 22-40
Author(s):  
Mikael John A. Baltazar ◽  
Roy Kristian C. Yanela ◽  
Armando, Jr, M. Guidote ◽  
Noriyuki Suzuki
Keyword(s):  
Organometallic Chemistry ◽  
Organic Synthesis ◽  
Reducing Agent ◽  
Allylic Alcohols ◽  
Reaction Systems ◽  
Effective Catalyst ◽  
Tin Chloride ◽  
Palladium Catalyzed ◽  
Carbonyl Allylation ◽  
Organic As

The treatment of allylic alcohols as synthons of carbanions for carbonyl allylation reactions in the presence of a Pd-SnCl2 system has been one of the most interesting and most useful developments demonstrated by Yoshiro Masuyama and co-workers in the field of organic synthesis. The reaction makes use of palladium as an effective catalyst and tin (II) chloride as a low-valent reducing agent which also effectively transforms the allylic group to a nucleophilic group. The organic, as well as organometallic, chemistry of how the transformations occur and how the metals take part in the reaction is of great interest. These could help allow for better optimization of reagents and solvents, for better control of the extent of reaction or yield of desired product, and for possible applications in other reaction systems. This review will focus primarily on the work of Yoshiro Masuyama and various co-workers on carbonyl allylation reactions making use of a Pd-SnCl2 system or substitutes thereof.

Ultrasound-promoted palladium-catalyzed carbonyl allylation by allylic alcohols with tin(II) chloride in non-polar solvents

1994 ◽  
Vol 220 (1-2) ◽  
pp. 155-159 ◽  
Author(s):  
Yoshiro Masuyama ◽  
Akiko Hayakawa ◽  
Masayuki Kishida ◽  
Yasuhiko Kurusu
Keyword(s):  
Allylic Alcohols ◽  
Polar Solvents ◽  
Palladium Catalyzed ◽  
Carbonyl Allylation

ChemInform Abstract: Palladium-Catalyzed Carbonyl Allylation by Allylic Alcohols with SnCl2.

ChemInform ◽  
2010 ◽  
Vol 23 (31) ◽  
pp. no-no
Author(s):  
J. P. TAKAHARA ◽  
Y. MASUYAMA ◽  
Y. KURUSU
Keyword(s):  
Allylic Alcohols ◽  
Palladium Catalyzed ◽  
Carbonyl Allylation
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