Physical Organic Chemistry of Transition Metal Carbene Complexes. 21.1Kinetics and Mechanism of Hydrolysis of (CO)5MC(SR)Ar (M = Cr and W; R = CH3and CH3CH2CH2; Ar = C6H5and 3-ClC6H4) in Aqueous Acetonitrile. Important Differences Relative to Complexes with Alkoxy Leaving Groups

Claude F. Bernasconi; Gabriel S. Perez

doi:10.1021/ja002371l

Physical Organic Chemistry of Transition Metal Carbene Complexes. 21.1Kinetics and Mechanism of Hydrolysis of (CO)5MC(SR)Ar (M = Cr and W; R = CH3and CH3CH2CH2; Ar = C6H5and 3-ClC6H4) in Aqueous Acetonitrile. Important Differences Relative to Complexes with Alkoxy Leaving Groups

Journal of the American Chemical Society ◽

10.1021/ja002371l ◽

2000 ◽

Vol 122 (50) ◽

pp. 12441-12446 ◽

Cited By ~ 11

Author(s):

Claude F. Bernasconi ◽

Gabriel S. Perez

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Mechanism Of Hydrolysis ◽

Leaving Groups ◽

Hydrolysis Of

Physical Organic Chemistry of Transition Metal Carbene Complexes. 5. Kinetics and Mechanism of Hydrolysis of (CO)5Cr:C(OCH3)CH3 and (CO)5Cr:C(OCH2CH3)CH3 in Aqueous Acetonitrile

Journal of the American Chemical Society ◽

10.1021/ja00122a019 ◽

1995 ◽

Vol 117 (17) ◽

pp. 4875-4880 ◽

Cited By ~ 11

Author(s):

Claude F. Bernasconi ◽

Francis X. Flores ◽

Weitao Sun

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Kinetics And Mechanism ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Mechanism Of Hydrolysis ◽

Hydrolysis Of

Physical Organic Chemistry of Transition Metal Carbene Complexes. 6. Kinetics and Mechanism of the Thermal and Photochemical Hydrolysis of (CO)5M:C(OMe)CH2Ph (M = Cr, W) in Aqueous Acetonitrile

Organometallics ◽

10.1021/om00012a030 ◽

1995 ◽

Vol 14 (12) ◽

pp. 5615-5621 ◽

Cited By ~ 6

Author(s):

Claude F. Bernasconi ◽

Weitao Sun

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Kinetics And Mechanism ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Hydrolysis Of

ChemInform Abstract: Physical Organic Chemistry of Transition Metal Carbene Complexes. Part 11. Kinetics and Mechanism of the Hydrolysis of (2-Oxacyclopentylidene) pentacarbonylchromium(0) in Aqueous Acetonitrile.

ChemInform ◽

10.1002/chin.199748219 ◽

2010 ◽

Vol 28 (48) ◽

pp. no-no

Author(s):

C. F. BERNASCONI ◽

A. E. LEYES

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Kinetics And Mechanism ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Hydrolysis Of

Physical Organic Chemistry of Transition Metal Carbene Complexes. 13.1Kinetics of Proton Transfer from (5-Methyl-2-oxacyclopentylidene)pentacarbonylchromium(0) and Hydrolysis of Its Conjugate Anion in Aqueous Acetonitrile

Organometallics ◽

10.1021/om980444s ◽

1998 ◽

Vol 17 (23) ◽

pp. 4940-4945 ◽

Cited By ~ 6

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes ◽

Luis García-Río

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Proton Transfer ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Hydrolysis Of

Physical organic chemistry of transition metal carbene complexes. Part 11.1 Kinetics and mechanism of the hydrolysis of (2-oxacyclopentylidene)pentacarbonylchromium(0) in aqueous acetonitrile

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/a702286g ◽

1997 ◽

pp. 1641-1648 ◽

Cited By ~ 9

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Kinetics And Mechanism ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Hydrolysis Of

Physical Organic Chemistry of Transition Metal Carbene Complexes. 7.1Kinetics of Hydrolysis of (CO)5MC(OR)Ph (M = Cr, W; R = Me, Et) and (CO)5Cr(OMe)CHCHPh in Aqueous Acetonitrile

Journal of the American Chemical Society ◽

10.1021/ja963617i ◽

1997 ◽

Vol 119 (9) ◽

pp. 2103-2110 ◽

Cited By ~ 22

Author(s):

Claude F. Bernasconi ◽

Francis X. Flores ◽

Kevin W. Kittredge

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Hydrolysis Of

Physical Organic Chemistry of Transition Metal Carbene Complexes. 8.1Kinetic and Thermodynamic Acidities of Alkoxyalkylcarbene Pentacarbonyl Complexes of Cr, Mo, and W in Aqueous Acetonitrile. Dependence on Metal, Alkyl Group, and Alkoxy Group

Organometallics ◽

10.1021/om960936+ ◽

1997 ◽

Vol 16 (9) ◽

pp. 1926-1932 ◽

Cited By ~ 13

Author(s):

Claude F. Bernasconi ◽

Weitao Sun

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Alkyl Group ◽

Alkoxy Group ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic

Physical Organic Chemistry of Transition Metal Carbene Complexes. 25. Kinetic and Thermodynamic Acidities of Substituted (Methylthiophenylcarbene)pentacarbonyl Tungsten(0) and (Benzoxymethylcarbene)pentacarbonyl Tungsten(0) in Aqueous Acetonitrile. Evidence for Transition State Imbalances†

Journal of the American Chemical Society ◽

10.1021/ja020665w ◽

2002 ◽

Vol 124 (50) ◽

pp. 14968-14976 ◽

Cited By ~ 11

Author(s):

Claude F. Bernasconi ◽

Viola Ruddat

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Transition State ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic

Physical Organic Chemistry of Transition Metal Carbene Complexes. 9.1Thermodynamic and Kinetic Acidity of (2-Oxacyclopentylidene)pentacarbonylchromium(0) in Aqueous Acetonitrile

Journal of the American Chemical Society ◽

10.1021/ja964069b ◽

1997 ◽

Vol 119 (22) ◽

pp. 5169-5175 ◽

Cited By ~ 13

Author(s):

Claude F. Bernasconi ◽

Aquiles E. Leyes

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Physical Organic ◽

Kinetic Acidity

Physical Organic Chemistry of Transition Metal Carbene Complexes. 22.1Substituent Effects on the Reversible Cyclization of Fischer Carbene Complexes (CO)5WC(SCH2CH2OH)C6H4Z in Aqueous Acetonitrile

Organometallics ◽

10.1021/om010364f ◽

2001 ◽

Vol 20 (16) ◽

pp. 3383-3389 ◽

Cited By ~ 5

Author(s):

Claude F. Bernasconi ◽

Mahammad Ali

Keyword(s):

Organic Chemistry ◽

Transition Metal ◽

Physical Organic Chemistry ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Aqueous Acetonitrile ◽

Fischer Carbene ◽

Physical Organic ◽

Reversible Cyclization