Reactions leading to formation and cleavage of metal-metal and metal-.mu.-phosphido bonds in binuclear molybdenum and tungsten complexes. Structural analyses of W2(CO)8(.mu.-PPh2)2 and its two-electron reduction product, [Li(THF)3]2[W2(CO)8(.mu.-PPh2)2]

Journal of the American Chemical Society ◽

10.1021/ja00246a018 ◽

1987 ◽

Vol 109 (12) ◽

pp. 3617-3625 ◽

Author(s):

Shin Guang Shyu ◽

Mario Calligaris ◽

Giorgio Nardin ◽

Andrew Wojcicki

Keyword(s):

Reduction Product ◽

Tungsten Complexes ◽

Metal Metal ◽

Electron Reduction ◽

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ChemInform Abstract: Reactions Leading to Formation and Cleavage of Metal-Metal and Metal-μ-Phosphido Bonds in Binuclear Molybdenum and Tungsten Complexes. Structural Analyses of W2(CO)8(μ-PPh2)2 and Its Two-Electron Reduction Product, (Li(THF)3)2(W2(CO)8

10.1002/chin.198741280 ◽

1987 ◽

Vol 18 (41) ◽

Author(s):

S.-G. SHYU ◽

M. CALLIGARIS ◽

G. NARDIN ◽

A. WOJCICKI

Keyword(s):

Reduction Product ◽

Tungsten Complexes ◽

Metal Metal ◽

Electron Reduction ◽

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Mono- and binuclear molybdenum and tungsten complexes containing asymmetric bridging ligands: effects of ligand conjugation and conformation on metal-metal interactions

Inorganic Chemistry ◽

10.1021/ic00062a045 ◽

1993 ◽

Vol 32 (10) ◽

pp. 2145-2155 ◽

Author(s):

Amitava Das ◽

John C. Jeffery ◽

John P. Maher ◽

Jon A. McCleverty ◽

Erik Schatz ◽

...

Keyword(s):

Bridging Ligands ◽

Metal Interactions ◽

Tungsten Complexes ◽

Metal Metal ◽

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Dinuclear Molybdenum and Tungsten Complexes with Metal−Metal Triple Bonds Supported byp-tert-Butylcalix[4]arene Ligands

Inorganic Chemistry ◽

10.1021/ic990513a ◽

1999 ◽

Vol 38 (23) ◽

pp. 5219-5229 ◽

Author(s):

Malcolm H. Chisholm ◽

Kirsten Folting ◽

William E. Streib ◽

De-Dong Wu

Keyword(s):

Triple Bonds ◽

Arene Ligands ◽

Tungsten Complexes ◽

Metal Metal ◽

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Electrochemical and ESR studies of molybdenum-sulfur donor complexes. One-electron reduction of [cis-bis(N,N-dialkyldithiocarbamato)dinitrosyl]molybdenum and -tungsten complexes

Inorganic Chemistry ◽

10.1021/ic00133a032 ◽

1982 ◽

Vol 21 (3) ◽

pp. 1031-1036 ◽

Author(s):

John R. Budge ◽

John A. Broomhead ◽

Peter D. W. Boyd

Keyword(s):

Tungsten Complexes ◽

Electron Reduction ◽

Sulfur Donor ◽

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ChemInform Abstract: ELECTROCHEMICAL AND ESR STUDIES OF MOLYBDENUM-SULFUR DONOR COMPLEXES. ONE-ELECTRON REDUCTION OF (CIS-BIS(N,N-DIALKYLDITHIOCARBAMATO)DINITROSYL)MOLYBDENUM AND -TUNGSTEN COMPLEXES

Chemischer Informationsdienst ◽

10.1002/chin.198224290 ◽

1982 ◽

Vol 13 (24) ◽

Author(s):

J. R. BUDGE ◽

J. A. BROOMHEAD ◽

P. D. W. BOYD

Keyword(s):

Tungsten Complexes ◽

Electron Reduction ◽

Sulfur Donor ◽

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Preparation and characterization of the kinetic and thermodynamic isomers of dinuclear molybdenum and tungsten complexes with metal–metal triple bonds supported by p-tert-butylcalix[4]arene anions†

Chemical Communications ◽

10.1039/a708268a ◽

1998 ◽

pp. 379-380 ◽

Author(s):

Malcolm H. Chisholm ◽

Kirsten Folting ◽

De-Dong Wu

Keyword(s):

Triple Bonds ◽

Tungsten Complexes ◽

Metal Metal ◽

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ChemInform Abstract: The Novel Reaction of Metal-Metal Triple-Bonded Complexes and Nitro Compounds. Decarbonylation and the Formation of High Oxidation State Molybdenum and Tungsten Complexes Bearing Bridging and Terminal Oxygen Ligands.

Chemischer Informationsdienst ◽

10.1002/chin.198339289 ◽

1983 ◽

Vol 14 (39) ◽

Author(s):

H. ALPER ◽

J.-F. PETRIGNANI ◽

F. W. B. EINSTEIN ◽

A. C. WILLIS

Keyword(s):

Oxidation State ◽

Nitro Compounds ◽

The Novel ◽

High Oxidation State ◽

Tungsten Complexes ◽

Metal Metal ◽

High Oxidation ◽

And Tungsten ◽

Bonded Complexes

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Novel reaction of metal-metal triple-bonded complexes and nitro compounds. Decarbonylation and the formation of high oxidation state molybdenum and tungsten complexes bearing bridging and terminal oxygen ligands

Journal of the American Chemical Society ◽

10.1021/ja00344a074 ◽

1983 ◽

Vol 105 (6) ◽

pp. 1701-1702 ◽

Author(s):

Howard Alper ◽

Anthony C. Willis ◽

Jean Francois Petrignani ◽

Frederick W. B. Einstein

Keyword(s):

Oxidation State ◽

Nitro Compounds ◽

High Oxidation State ◽

Tungsten Complexes ◽

Metal Metal ◽

High Oxidation ◽

And Tungsten ◽

Bonded Complexes

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Novel synthesis of reduced mixed-valence molybdenum and tungsten complexes by electrochemical oxidation of the seven-coordinate complexes MX(S2)(R2dtc)2 (M = Mo, X = O; M = W, X = O, S; R = alkyl; dtc = dithiocarbamate)

Inorganic Chemistry ◽

10.1021/ic00279a008 ◽

1988 ◽

Vol 27 (6) ◽

pp. 978-985 ◽

Author(s):

A. M. Bond ◽

J. A. Broomhead ◽

A. F. Hollenkamp

Keyword(s):

Electrochemical Oxidation ◽

Mixed Valence ◽

Tungsten Complexes ◽

Novel Synthesis ◽

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Eine effiziente Synthesemethode für DiarylallenyIiden(pentacarbonyl)chrom- und -wolfram-Komplexe -Kristallstruktur von (CO)5Cr=C=C=CPh2 / An efficient Synthesis of Diarylallenylidene Pentacarbonyl Chromium and Tungsten Complexes - Crystal Structure of (CO)5Cr=C=C=CPh2

Zeitschrift für Naturforschung B ◽

10.1515/znb-1994-0909 ◽

1994 ◽

Vol 49 (9) ◽

pp. 1207-1214 ◽

Author(s):

Helmut Fischer ◽

David Reindl ◽

Gerhard Roth

Keyword(s):

Crystal Structure ◽

Structure Analysis ◽

Efficient Synthesis ◽

X Ray ◽

Tungsten Complexes ◽

An efficient synthesis of diarylallenylidene pentacarbonyl chromium and tungsten complexes is presented. Irradiation of M(CO)6 in THF affords (CO)sM[THF], Substitution of the THF ligand by diarylpropargylalcoholate and subsequent desoxygenation with COCF gives the title compounds in good yield. (The structure of diphenylallenylidene pentacarbonyl chromium has been determined by X-ray structure analysis

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