Thermolysis of model compounds for coal. Part 5. Enhancement of free-radical chain rearrangement, cyclization, and hydrogenolysis during thermolysis of surface-immobilized bibenzyl. Implications for coal chemistry

1986 ◽  
Vol 108 (24) ◽  
pp. 7703-7715 ◽  
Author(s):  
A. C. Buchanan ◽  
T. Don J. Dunstan ◽  
Emily C. Douglas ◽  
Marvin L. Poutsma
Keyword(s):  
Free Radical ◽  
Model Compounds ◽  
Radical Chain ◽  
Coal Chemistry

ChemInform Abstract: New Free-Radical Chain Processes Involving Substitution of Vinyl and Aryl Chlorides by Alkanes, Alkenes, Esters, and Ethers.

ChemInform ◽  
2010 ◽  
Vol 28 (4) ◽  
pp. no-no
Author(s):  
S. ARANEO ◽  
R. ARRIGONI ◽  
H.-R. BJOERSVIK ◽  
F. FONTANA ◽  
L. LIGUORI ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Chain ◽  
Aryl Chlorides ◽  
Chain Processes

scholarly journals The detection and inhibition of free radical chain reactions

1942 ◽  
Vol 180 (982) ◽  
pp. 237-256 ◽  
Keyword(s):  
Nitric Oxide ◽  
Free Radical ◽  
Chemical Analysis ◽  
Diethyl Ether ◽  
Pressure Increase ◽  
Stationary States ◽  
Decomposition Rates ◽  
Radical Chain ◽  
Chain Reactions ◽  
Limiting Values

Part I. Comparison of nitric oxide and propylene as inhibitors The reduction by propylene of the rate of pressure increase in the decomposition of propaldehyde at 550° has been shown by chemical analysis to represent a true inhibition of the reaction, and not to be due n an important degree to an induced polymerization of the propylene. With propaldehyde and with diethyl ether the limiting values to which the decomposition rates are reduced by nitric oxide and by propylene respectively are the same, although much more propylene is required to produce a given degree of inhibition. From this it is concluded that the limiting rates are more probably those of independent non-chain processes, than those characteristic of stationary states where the inhibitor starts and stops chains with equal efficiency.

The reaction of thionitrites with barton esters: a convenient free radical chain reaction for decarboxylative nitrosation

Tetrahedron ◽  
1999 ◽  
Vol 55 (12) ◽  
pp. 3573-3584 ◽  
Author(s):  
Pierre Girard ◽  
Nadine Guillot ◽  
William B. Motherwell ◽  
Robyn S. Hay-Motherwell ◽  
Pierre Potier
Keyword(s):  
Free Radical ◽  
Chain Reaction ◽  
Radical Chain ◽  
Free Radical Chain Reaction ◽  
Radical Chain Reaction

ChemInform Abstract: COAL CHEMISTRY. 8. REACTIONS OF TETRALIN WITH COAL AND WITH SOME CARBON-14-CONTAINING MODEL COMPOUNDS

1979 ◽  
Vol 10 (47) ◽  
Author(s):  
C. J. COLLINS ◽  
V. F. RAAEN ◽  
B. M. BENJAMIN ◽  
P. H. MAUPIN ◽  
W. H. ROARK
Keyword(s):  
Model Compounds ◽  
Carbon 14 ◽  
Coal Chemistry
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