Some Factors Influencing the Ultraviolet Absorption Spectra of Polynuclear Aromatic Compounds. II. The Spectra of Aryl Carbinols and Polybenzfluorenes

1945 ◽  
Vol 67 (11) ◽  
pp. 2021-2027 ◽  
Author(s):  
R. Norman Jones

1972 ◽  
Vol 25 (1) ◽  
pp. 171 ◽  
Author(s):  
T Teitei ◽  
PJ Collin ◽  
WHF Sasse

Eight heterocyclic diarylacetylenes derived from pyridine, furan, thiophen, and thiazole have been irradiated in the presence of naphthalene. Phenyl(4-pyridyl)- acetylene gave the compounds (2a) and (2b), phenyl(3-pyridyl)acetylene gave the compounds (3a) and (3b), and phenyl(2-pyridyl)acetylene compounds (4a) and (4b). From 1-methylnaphthalene and phenyl(3-pyridyl)acetylene the adducts (5a) and (5b) have been isolated and two adducts which formed by addition to the unsubstituted ring were detected. From phenyl(2-thiazolyl)acetylene and naphthalene probably only one isomeric adduct (6b) was isolated. The methiodides of all the new adducts except (6b) have been prepared. The structures proposed for these photo-adducts are based on their p.m.r., mass, and ultraviolet absorption spectra. Factors influencing the isomer distribution and overall yields are discussed in terms of a mechanism previously proposed for the addition of diphenylacetylene to naphthalene.



1957 ◽  
Vol 79 (19) ◽  
pp. 5138-5142 ◽  
Author(s):  
Melvin Robin ◽  
Kenneth N. Trueblood






2013 ◽  
Vol 779 (1) ◽  
pp. 40 ◽  
Author(s):  
Yu-Jong Wu ◽  
Hui-Fen Chen ◽  
Shiang-Jiun Chuang ◽  
Tzu-Ping Huang


1950 ◽  
Vol 187 (1) ◽  
pp. 299-312
Author(s):  
R.L. Sinsheimer ◽  
J.F. Scott ◽  
J.R. Loofbourow






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