Experimental Evidence for Chair-Like Transition States in Aldol Reactions of Methyl Ketone Lithium Enolates:  Stereoselective Synthesis and Utilization of a Deuterium-Labeled Enolate as a Probe of Reaction Stereochemistry

2005 ◽  
Vol 127 (16) ◽  
pp. 5770-5771 ◽  
Author(s):  
Christopher M. Liu ◽  
William J. Smith ◽  
Darin J. Gustin ◽  
William R. Roush
Keyword(s):  
Experimental Evidence ◽  
Methyl Ketone ◽  
Stereoselective Synthesis ◽  
Transition States ◽  
Aldol Reactions ◽  
Lithium Enolates

ChemInform Abstract: Design and Evaluation of a Practical Camphor-Based Methyl Ketone Enolate for Highly Stereoselective “Acetate” Aldol Reactions.

ChemInform ◽  
2010 ◽  
Vol 29 (19) ◽  
pp. no-no
Author(s):  
C. PALOMO ◽  
A. GONZALEZ ◽  
J. M. GARCIA ◽  
C. LANDA ◽  
M. OIARBIDE ◽  
...  
Keyword(s):  
Methyl Ketone ◽  
Aldol Reactions

Aggregation and Cooperative Effects in the Aldol Reactions of Lithium Enolates

2013 ◽  
Vol 19 (41) ◽  
pp. 13761-13773 ◽  
Author(s):  
Olatz Larrañaga ◽  
Abel de Cózar ◽  
F. Matthias Bickelhaupt ◽  
Ronen Zangi ◽  
Fernando P. Cossío
Keyword(s):  
Aldol Reactions ◽  
Cooperative Effects ◽  
Lithium Enolates

Double stereodifferentiating aldol reactions of (E) and (Z) lithium enolates. Model reactions for polypropionate assemblage

1996 ◽  
Vol 37 (12) ◽  
pp. 1957-1960 ◽  
Author(s):  
David A. Evans ◽  
Michael G. Yang ◽  
Michael J. Dart ◽  
Joseph L. Duffy
Keyword(s):  
Aldol Reactions ◽  
Lithium Enolates ◽  
Model Reactions
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