Rhodium-Catalyzed Allylic Substitution with an Acyl Anion Equivalent: Stereospecific Construction of Acyclic Quaternary Carbon Stereogenic Centers

2012 ◽  
Vol 134 (47) ◽  
pp. 19314-19317 ◽  
Author(s):  
P. Andrew Evans ◽  
Samuel Oliver ◽  
Jungha Chae
Keyword(s):  
Allylic Substitution ◽  
Quaternary Carbon ◽  
Stereogenic Centers ◽  
Acyl Anion

scholarly journals N-Substituted tertiary and O-substituted quaternary carbon stereogenic centers by site-, diastereo- and enantioselective vinylogous Mannich reactions

2015 ◽  
Vol 56 (23) ◽  
pp. 3489-3493 ◽  
Author(s):  
Daniel L. Silverio ◽  
Peng Fu ◽  
Emma L. Carswell ◽  
Marc L. Snapper ◽  
Amir H. Hoveyda
Keyword(s):  
Quaternary Carbon ◽  
Mannich Reactions ◽  
Stereogenic Centers

1,3-Dithianes as Acyl Anion Equivalents in Pd-Catalyzed Asymmetric Allylic Substitution

2016 ◽  
Vol 18 (24) ◽  
pp. 6296-6299 ◽  
Author(s):  
Kun Yao ◽  
Delong Liu ◽  
Qianjia Yuan ◽  
Tsuneo Imamoto ◽  
Yangang Liu ◽  
...  
Keyword(s):  
Allylic Substitution ◽  
Acyl Anion

Regio‐ and Enantioselective Synthesis of Sulfone‐Bearing Quaternary Carbon Stereocenters by Pd‐Catalyzed Allylic Substitution

2019 ◽  
Vol 132 (3) ◽  
pp. 1356-1361 ◽  
Author(s):  
Ajmal Khan ◽  
Heng Zhao ◽  
Meina Zhang ◽  
Shahid Khan ◽  
Depeng Zhao
Keyword(s):  
Enantioselective Synthesis ◽  
Allylic Substitution ◽  
Quaternary Carbon
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