Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition

In Su Kim; Ming-Yu Ngai; Michael J. Krische

doi:10.1021/ja805722e

Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition

Journal of the American Chemical Society ◽

10.1021/ja805722e ◽

2008 ◽

Vol 130 (44) ◽

pp. 14891-14899 ◽

Cited By ~ 197

Author(s):

In Su Kim ◽

Ming-Yu Ngai ◽

Michael J. Krische

Keyword(s):

Allyl Acetate ◽

Oxidation Level ◽

Carbonyl Addition ◽

Carbonyl Allylation ◽

Aldehyde Oxidation ◽

Metal Reagents

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ChemInform Abstract: Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenation Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition.

ChemInform ◽

10.1002/chin.200912053 ◽

2009 ◽

Vol 40 (12) ◽

Author(s):

In Su Kim ◽

Ming-Yu Ngai ◽

Michael J. Krische

Keyword(s):

Transfer Hydrogenation ◽

Allyl Acetate ◽

Oxidation Level ◽

Carbonyl Addition ◽

Carbonyl Allylation ◽

Aldehyde Oxidation ◽

Metal Reagents

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Ruthenium-Catalyzed C−C Bond Forming Transfer Hydrogenation: Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Employing Acyclic 1,3-Dienes as Surrogates to Preformed Allyl Metal Reagents

Journal of the American Chemical Society ◽

10.1021/ja801213x ◽

2008 ◽

Vol 130 (20) ◽

pp. 6338-6339 ◽

Cited By ~ 136

Author(s):

Fumitoshi Shibahara ◽

John F. Bower ◽

Michael J. Krische

Keyword(s):

Transfer Hydrogenation ◽

Oxidation Level ◽

Bond Forming ◽

Carbonyl Allylation ◽

Aldehyde Oxidation ◽

Metal Reagents

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Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Using Allyl Acetate as an Allyl Metal Surrogate

Journal of the American Chemical Society ◽

10.1021/ja802001b ◽

2008 ◽

Vol 130 (20) ◽

pp. 6340-6341 ◽

Cited By ~ 170

Author(s):

In Su Kim ◽

Ming-Yu Ngai ◽

Michael J. Krische

Keyword(s):

Allyl Acetate ◽

Oxidation Level ◽

Carbonyl Allylation ◽

Aldehyde Oxidation

Download Full-text

ChemInform Abstract: Ruthenium-Catalyzed C-C Bond Forming Transfer Hydrogenation: Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Employing Acyclic 1,3-Dienes as Surrogates to Preformed Allyl Metal Reagents.

ChemInform ◽

10.1002/chin.200840074 ◽

2008 ◽

Vol 39 (40) ◽

Author(s):

Fumitoshi Shibahara ◽

John F. Bower ◽

Michael J. Krische

Keyword(s):

Transfer Hydrogenation ◽

Oxidation Level ◽

Bond Forming ◽

Carbonyl Allylation ◽

Aldehyde Oxidation ◽

Metal Reagents

Download Full-text

ChemInform Abstract: Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Using Allyl Acetate as an Allyl Metal Surrogate.

ChemInform ◽

10.1002/chin.200840075 ◽

2008 ◽

Vol 39 (40) ◽

Author(s):

In Su Kim ◽

Ming-Yu Ngai ◽

Michael J. Krische

Keyword(s):

Allyl Acetate ◽

Oxidation Level ◽

Carbonyl Allylation ◽

Aldehyde Oxidation

Download Full-text

ChemInform Abstract: Formation of C-C Bonds via Ruthenium-Catalyzed Transfer Hydrogenation: Carbonyl Addition from the Alcohol or Aldehyde Oxidation Level

ChemInform ◽

10.1002/chin.200910236 ◽

2009 ◽

Vol 40 (10) ◽

Author(s):

Fumitoshi Shibahara ◽

Michael J. Krische

Keyword(s):

Transfer Hydrogenation ◽

Oxidation Level ◽

Carbonyl Addition ◽

Aldehyde Oxidation

Download Full-text

ChemInform Abstract: anti-Diastereo- and Enantioselective Carbonyl Crotylation from the Alcohol or Aldehyde Oxidation Level Employing a Cyclometalated Iridium Catalyst: α-Methyl Allyl Acetate as a Surrogate to Preformed Crotylmetal Reagents.

ChemInform ◽

10.1002/chin.200927059 ◽

2009 ◽

Vol 40 (27) ◽

Author(s):

In Su Kim ◽

Soo Bong Han ◽

Michael J. Krische

Keyword(s):

Allyl Acetate ◽

Oxidation Level ◽

Iridium Catalyst ◽

Aldehyde Oxidation

Download Full-text

anti-Diastereo- and Enantioselective Carbonyl Crotylation from the Alcohol or Aldehyde Oxidation Level Employing a Cyclometallated Iridium Catalyst: α-Methyl Allyl Acetate as a Surrogate to Preformed Crotylmetal Reagents

Journal of the American Chemical Society ◽

10.1021/ja808857w ◽

2009 ◽

Vol 131 (7) ◽

pp. 2514-2520 ◽

Cited By ~ 131

Author(s):

In Su Kim ◽

Soo Bong Han ◽

Michael J. Krische

Keyword(s):

Allyl Acetate ◽

Oxidation Level ◽

Iridium Catalyst ◽

Aldehyde Oxidation

Download Full-text

Formation of C–C Bonds via Ruthenium-catalyzed Transfer Hydrogenation: Carbonyl Addition from the Alcohol or Aldehyde Oxidation Level

Chemistry Letters ◽

10.1246/cl.2008.1102 ◽

2008 ◽

Vol 37 (11) ◽

pp. 1102-1107 ◽

Cited By ~ 62

Author(s):

Fumitoshi Shibahara ◽

Michael J. Krische

Keyword(s):

Transfer Hydrogenation ◽

Oxidation Level ◽

Carbonyl Addition ◽

Aldehyde Oxidation

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ChemInform Abstract: Iridium-Catalyzed C-C Coupling via Transfer Hydrogenation: Carbonyl Addition from the Alcohol or Aldehyde Oxidation Level Employing 1,3-Cyclohexadiene.

ChemInform ◽

10.1002/chin.200832091 ◽

2008 ◽

Vol 39 (32) ◽

Author(s):

John F. Bower ◽

Ryan L. Patman ◽

Michael J. Krische

Keyword(s):

Transfer Hydrogenation ◽

Oxidation Level ◽

Carbonyl Addition ◽

Aldehyde Oxidation

Download Full-text