Anionic Polymerization of (Meth)acrylates in the Presence of Tetraalkylammonium Halide−Trialkyl Aluminum Complexes in Toluene, 1. Kinetic Investigations with Methyl Methacrylate

1998 ◽  
Vol 31 (21) ◽  
pp. 7127-7132 ◽  
Author(s):  
Helmut Schlaad ◽  
Axel H. E. Müller
Keyword(s):  
Methyl Methacrylate ◽  
Anionic Polymerization ◽  
Tetraalkylammonium Halide ◽  
Aluminum Complexes ◽  
Kinetic Investigations

scholarly journals Anionic polymerization of (meth)acrylic monomers. 7. Macrocyclic crown ethers as promoters of the living polymerization of methyl methacrylate using monofunctional initiators

1992 ◽  
Vol 25 (18) ◽  
pp. 4457-4463 ◽  
Author(s):  
Sunil K. Varshney ◽  
Robert Jerome ◽  
Philippe Bayard ◽  
Christian Jacobs ◽  
Roger Fayt ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Crown Ethers ◽  
Anionic Polymerization ◽  
Living Polymerization ◽  
Acrylic Monomers

scholarly journals Synthesis and post-polymerization reaction of end-clickable stereoregular polymethacrylates via termination of stereospecific living anionic polymerization

2015 ◽  
Vol 6 (7) ◽  
pp. 1078-1087 ◽  
Author(s):  
Yasuhiro Kohsaka ◽  
Takashi Kurata ◽  
Kazuki Yamamoto ◽  
Shoya Ishihara ◽  
Tatsuki Kitayama
Keyword(s):  
Methyl Methacrylate ◽  
Anionic Polymerization ◽  
Polymerization Reaction ◽  
Living Anionic Polymerization ◽  
Poly Methyl Methacrylate ◽  
End Groups

Poly(methyl methacrylate)s with high stereoregularity and clickable end-groups were synthesized via terminating reactions with α-(halomethyl)acrylates in stereospecific living anionic polymerization.

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