Binuclear zirconium(III) and zirconium(IV) complexes: mild oxidation of low-valent zirconium as a synthetic pathway to a class of tri- and tetravalent zirconium fulvalene complexes. Molecular structures of [.eta.5:.eta.5-C10H8][CpZrSPh]2, [.eta.5:.eta.5-C10H8][CpZr(CH3)2]2, and [.eta.5:.eta.5-C10H8][CpZr]2[.mu.-S]2

1990 ◽  
Vol 9 (7) ◽  
pp. 2142-2148 ◽  
Author(s):  
Ytsen Wielstra ◽  
Sandro Gambarotta ◽  
Anthony L. Spek ◽  
Wilberth J. J. Smeets
Keyword(s):  
Molecular Structures ◽  
Mild Oxidation ◽  
Synthetic Pathway ◽  
Low Valent

scholarly journals Non-bonded S · · · N Interactions in Organosulfur Derivatives: Crystal and Molecular Structures of [2-(4,4-Dimethyl-2-oxazolinyl)phenyl] Benzyl Sulfide and Bis[2-(4,4-dimethyl-2-oxazolinyl)phenyl] Sulfide

1999 ◽  
Vol 23 (8) ◽  
pp. 472-473
Author(s):  
G. Mugesh ◽  
Harkesh B. Singh ◽  
Ray J. Butcher
Keyword(s):  
Molecular Structures ◽  
Structural Characterisation ◽  
Phenyl Sulfide ◽  
Crystal And Molecular Structures ◽  
Low Valent

The synthesis and structural characterisation of two low-valent sulfur derivatives stabilised by S · · · N intramolecular non-bonded interactions are described.

scholarly journals New molecular architectures containing low-valent cluster centres with di- and trimetalated 2-vinylpyrazine ligands: synthesis and molecular structures of Ru5(CO)15(μ5-C4H2N2CHCH)(μ-H)2 and Ru8(CO)24(μ7-C4H2N2CHC)(μ-H)3

RSC Advances ◽  
2019 ◽  
Vol 9 (36) ◽  
pp. 21025-21030 ◽  
Author(s):  
Md. Monir Hossain ◽  
Nahid Akter ◽  
Shishir Ghosh ◽  
Vladimir N. Nesterov ◽  
Michael G. Richmond ◽  
...  
Keyword(s):  
Molecular Structures ◽  
Molecular Architectures ◽  
Low Valent ◽  
Bond Activations

Reaction of 2-vinylpyrazine with Ru3(CO)12 results in multiple C–H bond activations to afford Ru5 and Ru8 clusters.

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