C–H Bond Activation and Isoprene Polymerization by Rare-Earth-Metal Tetramethylaluminate Complexes Bearing Formamidinato N-Ancillary Ligands

2013 ◽  
Vol 32 (5) ◽  
pp. 1209-1223 ◽  
Author(s):  
Shima Hamidi ◽  
Lars N. Jende ◽  
H. Martin Dietrich ◽  
Cäcilia Maichle-Mössmer ◽  
Karl W. Törnroos ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Bond Activation ◽  
Earth Metal ◽  
Ancillary Ligands ◽  
Isoprene Polymerization

Rare-earth metal-promoted (double) C–H-bond activation of a lutidinyl-functionalized alkoxy ligand: formation of [ONC] pincer-type ligands and implications for isoprene polymerization

2020 ◽  
Vol 49 (6) ◽  
pp. 2004-2013 ◽  
Author(s):  
Dominic Diether ◽  
Melanie Meermann-Zimmermann ◽  
Karl W. Törnroos ◽  
Cäcilia Maichle-Mössmer ◽  
Reiner Anwander
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Bond Activation ◽  
Earth Metal ◽  
Isoprene Polymerization

Steric pressure enforces the formation of dianionic and trianionic pincer-type ligands involving a rare alkylidene moiety in the latter case.

C–H bond activation of N-heterocyclic carbene IMes by rare-earth metal alkyl complexes

2010 ◽  
Vol 695 (25-26) ◽  
pp. 2794-2797 ◽  
Author(s):  
Waldemar Fegler ◽  
Teruhiko Saito ◽  
Kazushi Mashima ◽  
Thomas P. Spaniol ◽  
Jun Okuda
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Bond Activation ◽  
Earth Metal ◽  
Alkyl Complexes

Rare‐Earth‐Metal Pentadienyl Half‐Sandwich and Sandwich Tetramethylaluminates–Synthesis, Structure, Reactivity, and Performance in Isoprene Polymerization

2019 ◽  
Vol 25 (18) ◽  
pp. 4821-4832 ◽  
Author(s):  
Damir Barisic ◽  
Dennis A. Buschmann ◽  
David Schneider ◽  
Cäcilia Maichle‐Mössmer ◽  
Reiner Anwander
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
And Performance ◽  
Half Sandwich ◽  
Isoprene Polymerization

Homoleptic Rare-Earth Metal(III) Tetramethylaluminates: Structural Chemistry, Reactivity, and Performance in Isoprene Polymerization

2007 ◽  
Vol 13 (31) ◽  
pp. 8784-8800 ◽  
Author(s):  
Melanie Zimmermann ◽  
Nils Åge Frøystein ◽  
Andreas Fischbach ◽  
Peter Sirsch ◽  
H. Martin Dietrich ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Structural Chemistry ◽  
And Performance ◽  
Isoprene Polymerization

Rare-earth metal bis(alkyl) complexes bearing pyrrolidinyl-functionalized cyclopentadienyl, indenyl and fluorenyl ligands: synthesis, characterization and the ligand effect on isoprene polymerization

2015 ◽  
Vol 39 (10) ◽  
pp. 7575-7581 ◽  
Author(s):  
Meng Deng ◽  
Shuhui Chi ◽  
Yunjie Luo
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Ligand Effect ◽  
Alkyl Complexes ◽  
Isoprene Polymerization

The ligand effect on isoprene polymerization was investigated using rare-earth metal bis(alkyl) complexes bearing pyrrolidinyl-functionalized cyclopentadienyl, indenyl and fluorenyl ligands.

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