Metal-metal double bond formation via steric design. Synthesis and x-ray crystal structure of [Rh(.mu.-tert-Bu2P)(CO)(PMe3)]2(Rh:Rh)

1983 ◽  
Vol 2 (12) ◽  
pp. 1842-1845 ◽  
Author(s):  
Richard A. Jones ◽  
Thomas C. Wright
Keyword(s):  
Crystal Structure ◽  
Double Bond ◽  
Bond Formation ◽  
Design Synthesis ◽  
X Ray ◽  
Metal Metal

Carbon–carbon bond formation through olefin–methylcarbyne linkage at a diruthenium centre: X-ray crystal structure of [Ru2(CO)(µ-CO){µ-η1,η3-C(Me)C(Me)CH2}(η-C5H5)2]

1981 ◽  
pp. 537-538 ◽  
Author(s):  
Andrew F. Dyke ◽  
Jacques E. Guerchais ◽  
Selby A. R. Knox ◽  
Jean Roué ◽  
Richard L. Short ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Bond Formation ◽  
Carbon Bond ◽  
X Ray ◽  
Carbon Carbon Bond

A dimeric cyano-rhenium complex with sulphur bridges and a sirect metalmetal bond: preparation and X-ray crystal structure of (Ph4P)4 [Re2(μ2-S)2-(CN)8]4−· 6H20

1978 ◽  
Vol 26 ◽  
pp. L27-L28 ◽  
Author(s):  
Michael Laing ◽  
Jaean-Marie Bregeault ◽  
William P. Griffith
Keyword(s):  
Crystal Structure ◽  
X Ray ◽  
Metal Bond ◽  
Rhenium Complex ◽  
Metal Metal

Design, Synthesis, and X-ray Crystal Structure of a Potent Dual Inhibitor of Thymidylate Synthase and Dihydrofolate Reductase as an Antitumor Agent1

2000 ◽  
Vol 43 (21) ◽  
pp. 3837-3851 ◽  
Author(s):  
Aleem Gangjee ◽  
Jianming Yu ◽  
John J. McGuire ◽  
Vivian Cody ◽  
Nikolai Galitsky ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Dihydrofolate Reductase ◽  
Thymidylate Synthase ◽  
Dual Inhibitor ◽  
Design Synthesis ◽  
X Ray

scholarly journals Über die Reaktion von Wolframhexachlorid mit Se4N2; Kristallstruktur von PPh4[WCl5(NSeCl)] / On the Reaction of Tungsten Hexachloride with Se4N2; Crystal Structure of PPh4[WCl5(NSeCl)]

1991 ◽  
Vol 46 (12) ◽  
pp. 1625-1628 ◽  
Author(s):  
Stefan Vogler ◽  
Werner Massa ◽  
Kurt Dehnicke
Keyword(s):  
Crystal Structure ◽  
Double Bond ◽  
Structure Determination ◽  
Space Group ◽  
X Ray ◽  
Bond Lengths ◽  
Tetraphenylphosphonium Chloride ◽  
Tungsten Hexachloride

The reaction of tungsten hexachloride with Se4N2 leads to [WCl4(NSeCl)]2, which reacts with pyridine to form [WCl4(NSeCl)Py], and with tetraphenylphosphonium chloride to form PPh4[WCl5(NSeCl)], which was characterized by an X-ray structure determination. Space group P21, Z = 2, 1657 observed unique reflections, R = 0.074, wR = 0.061. Lattice dimensions at —80 C: a = 710.7(1), b = 2217.9(4), c = 953.6(2) pm; β = 111.93(3) . The [WCl5(NSeCl)]- ion possesses an almost linear WNSe group with bond lengths WN = 188 pm, corresponding to a double bond, and NSe = 200 pm.

Design, synthesis and biological evaluation of novel human monoamine oxidase B inhibitors based on a fragment in an X-ray crystal structure

2019 ◽  
Vol 29 (8) ◽  
pp. 1012-1018 ◽  
Author(s):  
Kai Cheng ◽  
Shiyu Li ◽  
Xiao Lv ◽  
Yongbin Tian ◽  
Haiyan Kong ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Monoamine Oxidase ◽  
Biological Evaluation ◽  
Monoamine Oxidase B ◽  
Design Synthesis ◽  
X Ray ◽  
Synthesis And Biological Evaluation

Metal-metal bond formation and rearrangement of the S2CPR3 ligands in binuclear manganese-molybdenum complexes. X-ray structure of [MnMo(SnPh3)(CO)6(.mu.-S2CPPr-iso3)]

1993 ◽  
Vol 12 (8) ◽  
pp. 2888-2890 ◽  
Author(s):  
Daniel Miguel ◽  
Julio A. Perez-Martinez ◽  
Victor Riera ◽  
Santiago Garcia-Granda
Keyword(s):  
Bond Formation ◽  
Molybdenum Complexes ◽  
X Ray ◽  
Metal Bond ◽  
Metal Metal

Stereoselective carbon–carbon bond formation via alkylation of [(η-5C5H5)Fe(PPh3)(CO)(COMeCHR)](R = Me,Prn,Ph): X-ray crystal structure of (Z)-[(η5-C5H5)Fe(PPh3)(CO)(COMeCHMe)]

1984 ◽  
Vol 0 (12) ◽  
pp. 745-747 ◽  
Author(s):  
Gordon J. Baird ◽  
Stephen G. Davies ◽  
Richard H. Jones ◽  
Keith Prout ◽  
Peter Warner
Keyword(s):  
Crystal Structure ◽  
Bond Formation ◽  
Carbon Bond ◽  
X Ray ◽  
Carbon Carbon Bond

Tetraphenylphosphonium-nonachlorodivanadat(III), (PPh4)3[V2Cl9] · 7 CH2Cl2 / Tetraphenylphosphonium Nonachlorodivanadate(III), (PPh4)3[V2Cl9] · 7 CH2Cl2

1992 ◽  
Vol 47 (6) ◽  
pp. 814-818 ◽  
Author(s):  
Karin Ruhlandt-Senge ◽  
Alfred Dirk Bacher ◽  
Gertraude Koellner ◽  
Birgit Siewert ◽  
Ulrich Müller
Keyword(s):  
Crystal Structure ◽  
Structure Analysis ◽  
Crystal Structure Analysis ◽  
Crystal Data ◽  
X Ray ◽  
Metal Bonding ◽  
Metal Metal ◽  
Tetragonal Pyramidal ◽  
Approximate Composition ◽  
Insoluble Product

Reaction of VC14 with (Me3Si)2S in CH2C12 yields an insoluble product with the approximate composition VSC12. Its reaction with PPh4Cl in CH2Cl2 affords (PPh4)3[V2Cl9] · 7 CH2Cl2, whereas PPh4[VOCl4] is formed in the presence of oxygen. According to an X-ray crystal structure analysis, (PPh4)3[V2Cl9] · 7 CH2Cl2 contains [V2C19]3- ions having two face-sharing coordination octahedra but no significant metal-metal bonding (V-V distance 327.5 pm). Crystal data: a = 1386.4(7), b = 1405.6(7), c = 2710(2) pm, α = 95.800(5), β = 95.370(5), γ = 118.11(3)°, triclinic, Ρ 1̄, Ζ = 2; R = 0.066 for 8779 observed reflexions. PPh4[VOCl4] is isotypic with AsPh4[VOCl4] and contains tetragonal-pyramidal [VOCl4]- ions; tetragonal, P4/n, Z = 2, a = 1264.5(2), c = 772.0(2) pm; R = 0.050 for 654 observed reflexions.

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