metal bond
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Author(s):  
KaiNi Zhang ◽  
Hong Zheng ◽  
Mengyang Li ◽  
Yonghong Cheng ◽  
Xiang Zhao
Keyword(s):  


Author(s):  
Feng-lin Zhang ◽  
Gen-wei Huang ◽  
Jia-meng Liu ◽  
Zhi-jun Du ◽  
Shi-xiong Wu ◽  
...  


Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1375
Author(s):  
Marcin Gołąbczak ◽  
Andrzej Gołąbczak ◽  
Barbara Tomczyk

This article introduces significant cognitive and usable values in the field of abrasive technology especially in the development of new methods of the electrochemical dressing of superhard grinding wheels with metal bonds. Cognitive values mainly concern the elaboration of the theoretical backgrounds of the electrochemical digestion of compounds of grinding wheel metal bond and gumming up products of the cutting surface of grinding wheel (CSGW). Cognitive values also deal with determining the mathematical relationships describing the influence of technological conditions of dressing on shaping of cutting abilities of superhard grinding wheels. On the other hand, the useful values refer to the industry implementation of the elaborated method and equipment for the electrochemical dressing of suparhard grinding wheels using alternating current (ECDGW-AC). The cost of the device for the realization of this process is low and can be applied in the production conditions. The novel achievements presented in the article are: the elaboration of a new method and equipment for electrochemical dressing of superhard grinding wheels (ECDGW-AC), the selection of electrolytes of low concentration of chemical compounds, tests concerning the digestion of grinding wheel metal bond compounds and gumming up products of CSGW using X-ray analysis, as well as the determination of chemical reactions taking place during elaborated new dressing process, the elaboration of mathematical relationships describing influence of technological conditions of this process on dressing speed and shaping of cutting abilities of superhard grinding wheels, and the performance of technological tests of dressing of superhard grinding wheels using ECDGW-AC method. The elaborated method can be used in ambient temperature and does not cause thermal damages of abrasive grains of cutting surface of grinding wheel and is useful not only for dressing super hard grinding wheels but also for correcting their geometrical deviations.



2021 ◽  
Author(s):  
Jun Okuda ◽  
Louis J. Morris ◽  
Laurent Maron ◽  
Ambre Carpentier

Oxidative addition of TMEDA-supported [AlH2]+ to [{BDI}Ga] (BDI = {HC(C(CH3)N(2,6-iPr2-C6H3))2) provides [{BDI}Ga(H)-Al(H)(tmeda)]¬[B(C6H3-3,5-Me2)4] (TMEDA = N,N,N’N’-tetramethylethylene¬diamine) with a covalent metal-metal bond. The reaction is readily reversed by substituting TMEDA for an...



2021 ◽  
Author(s):  
Nathalie Ségaud ◽  
Chloë Johnson ◽  
Albert Farre ◽  
Martin Albrecht

The metal−carbon bond in N-heterocyclic carbene (NHC) metal complexes, which are ubiquitous in modern homogeneous catalysis, is often conjectured to be robust. Here, carbene dissociation was evaluated from a series...



2021 ◽  
Vol 50 (6) ◽  
pp. 2018-2022
Author(s):  
Guo Chen ◽  
Ting Fan ◽  
Bin Liu ◽  
Meng Xue ◽  
Jing-Jing Wei ◽  
...  

A water soluble and wide pH stability RuII,III2 diphosphonato complex with a metal–metal bond was applied to water oxidation.



2021 ◽  
Author(s):  
Shangfeng Yang ◽  
Fei Jin ◽  
Jinpeng Xin ◽  
Runnan Guan ◽  
Xiao-Ming Xie ◽  
...  

Trimetallic carbide clusterfullerenes (TCCFs) encapsulating a quinary M3C2 cluster represent a special family of endohedral fullerenes with open-shelled electronic configuration. Herein, a novel TCCF based on a medium-sized rare earth...



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