Rhenium sulfide cluster chemistry †

1999 ◽  
pp. 97-106 ◽  
Author(s):  
Taro Saito
Keyword(s):  
Cluster Chemistry ◽  
Rhenium Sulfide ◽  
Sulfide Cluster ◽  
Rhenium Sulfide Cluster

Paramagnetic triangular rhenium sulfide cluster [Re3S4(Dppe)3(NCS)3]Br

2014 ◽  
Vol 40 (4) ◽  
pp. 200-204 ◽  
Author(s):  
P. A. Petrov ◽  
M. Yu. Afonin ◽  
D. Yu. Naumov ◽  
A. S. Bogomyakov ◽  
S. N. Konchenko
Keyword(s):  
Rhenium Sulfide ◽  
Sulfide Cluster ◽  
Rhenium Sulfide Cluster

Catalytic ring-opening addition of thiols to epoxides in the gas-phase over molecular rhenium sulfide cluster complexes [Re6S8X6] (X=Cl, OH, H2O) with retention of their octahedral metal frameworks

2015 ◽  
Vol 497 ◽  
pp. 167-175 ◽  
Author(s):  
Sayoko Nagashima ◽  
Hiroshi Nagashima ◽  
Shota Furukawa ◽  
Satoshi Kamiguchi ◽  
Hideki Kurokawa ◽  
...  
Keyword(s):  
Gas Phase ◽  
Ring Opening ◽  
Cluster Complexes ◽  
Rhenium Sulfide ◽  
Sulfide Cluster ◽  
Rhenium Sulfide Cluster

Macropolyhedral Boron-Containing Cluster Chemistry. A Metallathiaborane from S2B17H17: Isolation and Characterisation of [(PMe2Ph)2PtS2B16H16]; A neo-arachno Ten-Vertex Cluster Shape, and the Constitution of the [arachno-B10H15]- Anion

2005 ◽  
Vol 70 (4) ◽  
pp. 430-440 ◽  
Author(s):  
Michael J. Carr ◽  
Michael G. S. Londesborough ◽  
Jonathan Bould ◽  
Ivana Císařová ◽  
Bohumil Štíbr ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Sodium Hydride ◽  
Hydrogen Atoms ◽  
Subsequent Reaction ◽  
Cluster Chemistry ◽  
Cluster Shape ◽  
Open Face

The deprotonation of S2B17H17 with sodium hydride and subsequent reaction with [PtCl2(PMe2Ph)2] gives the new macropolyhedral metallathiaborane [(PMe2Ph)2PtS2B16H16], of which the cluster consists of a conventional eleven-vertex nido {SB10} unit, fused, with two boron atoms in common, with a {PtSB8} unit of unique ten-vertex neo-arachno constitution and geometry. The latter geometry suggests a configuration for the previously structurally uncharacterised [B10H15]- anion; starting from this configuration, DFT calculations of structure and thence of boron nuclear shieldings, which are found very closely to mimic those found experimentally, thence support a fluxional structure for [B10H15]- with three {BHB(bridging)} and two {BH(endo)} hydrogen atoms around a six-membered open face.

A cobalt sulfide cluster-based catholyte for aqueous flow battery applications

2018 ◽  
Vol 6 (44) ◽  
pp. 21927-21932 ◽  
Author(s):  
Matthew B. Freeman ◽  
Le Wang ◽  
Daniel S. Jones ◽  
Christopher M. Bejger
Keyword(s):  
Active Material ◽  
Water Soluble ◽  
Molecular Cluster ◽  
Cobalt Sulfide ◽  
Redox Flow Battery ◽  
Flow Battery ◽  
Aqueous Flow ◽  
Sulfide Cluster

A water-soluble Co6S8 molecular cluster was prepared and electrochemically analyzed as a potential active material for redox flow battery applications.

ChemInform Abstract: Annual Survey of Organometallic Metal Cluster Chemistry for the Year 1998

ChemInform ◽  
2001 ◽  
Vol 32 (4) ◽  
pp. no-no
Author(s):  
Michael G. Richmond
Keyword(s):  
Metal Cluster ◽  
Cluster Chemistry ◽  
Annual Survey

Cluster Chemistry. VonG. González-Morega. Springer, Heidelberg, 1993. 302S., Broschur 98.00 DM. – ISBN 3-540-56470-5

1995 ◽  
Vol 107 (4) ◽  
pp. 539-539
Author(s):  
Lutz H. Gade
Keyword(s):  
Cluster Chemistry

Reactivity of an Arene Cobalt Triple Decker Complex Towards Various Ligands. Facile Arene Displacement in [Bis{( η5-pentamethylcyclopentadienyl)cobalt}-μ-{η4: η4-toluene}]

1995 ◽  
Vol 50 (7) ◽  
pp. 1055-1060 ◽  
Author(s):  
Jörg J. Schneider
Keyword(s):  
Room Temperature ◽  
Elemental Sulfur ◽  
Organic Ligands ◽  
Dinuclear Complexes ◽  
Sulfide Cluster

The triple decker complex [{(η5-Cp*)Co}2-μ-{η4: η4-toluene}] 1b exhibits an unusual reactivity towards a variety of organic ligands, 1b reacts with CO, ethene, butadiene, H2, Al2O3, hexafluorobenzene, 1.5 Cod, 2-butyne, phenanthrene, naphthalene and the dinuclear Ni cluster [{(η5-Cp)NiP(C2H5)3}2] to form mainly mononuclear organocobalt complexes. Reaction of 1b with NO and the diazoalkanes di-t-butyl-diazomethane and 2-diazo-1,1′,3,3′-tetramethylcyclohexane results in the formation of the dinuclear complexes [{(η5-Cp*)CoNO}2], [{(η5-Cp*)(di-t-butyl-diazomethane)Co}2] and [{(η5-Cp*)(2-diazo-1,1′,3,3′-tetramethylcyclohexane) Co}2], respectively. In the reaction of 1b with elemental sulfur the formation of a tetranuclear Co-sulfide cluster is observed. In the majority of the reactions studied, l b looses its toluene ligand already at room temperature indicating an unusual high and hitherto unprecedented reactivity of an arene triple decker complex.

The heteronuclear cluster chemistry of the Group IB metals

1988 ◽  
Vol 344 (3) ◽  
pp. 411-417 ◽  
Author(s):  
Paul J. McCarthy ◽  
Ian D. Salter ◽  
Vladimir Šik
Keyword(s):  
Cluster Chemistry ◽  
Heteronuclear Cluster

Cluster chemistry

1994 ◽  
Vol 469 (1) ◽  
pp. 89-97 ◽  
Author(s):  
Michael I. Bruce ◽  
Jonathan R. Hinchliffe ◽  
Richard Surynt ◽  
Brian W. Skelton ◽  
Allan H. White
Keyword(s):  
Cluster Chemistry

Analysis of the Bonding in[Ni5(μ5-S)(μ2-SR)5]−, an Unprecedented Pentanuclear Sulfide Cluster

1997 ◽  
Vol 36 (17) ◽  
pp. 1847-1849 ◽  
Author(s):  
Fu-Wah Cheung ◽  
Zhenyang Lin
Keyword(s):  
Sulfide Cluster
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