Synthesis and characterization of chelate and bridging triazenide complexes of palladium and platinum. Stereoselective oxidative addition of chlorine or iodine to [NBu4][Pt(C6F5)2(η2-PhNNNPh)]

Oxidative addition of oxygen-hydrogen bonds to iridium(I): synthesis and characterization of (phenolato)- and (carboxylato)iridium(III) hydride complexes

Inorganic Chemistry ◽

10.1021/ic00061a025 ◽

1993 ◽

Vol 32 (9) ◽

pp. 1681-1688 ◽

Cited By ~ 42

Author(s):

Folami T. Ladipo ◽

Mahimid Kooti ◽

Joseph S. Merola

Keyword(s):

Hydrogen Bonds ◽

Oxidative Addition ◽

Synthesis And Characterization ◽

Hydride Complexes

Synthesis and characterization of and stereoselective oxidative addition of chlorine or bromine to platinum complex, [NBu4][Pt(C6F5)2(C5H4NS)]

Organometallics ◽

10.1021/om00035a023 ◽

1993 ◽

Vol 12 (11) ◽

pp. 4368-4375 ◽

Cited By ~ 22

Author(s):

Juan Fornies ◽

Consuelo Fortuno ◽

Miguel A. Gomez ◽

Babil Menjon ◽

Eberhardt Herdtweck

Keyword(s):

Platinum Complex ◽

Oxidative Addition ◽

Synthesis And Characterization

The Halogen Effect in Oxidative Addition of Trimethylsilyl and Trimethyltin Halides to Platinum(II): Synthesis and Characterization of Silylplatinum(IV) Complexes

Organometallics ◽

10.1021/om00017a008 ◽

1994 ◽

Vol 13 (5) ◽

pp. 1559-1560 ◽

Cited By ~ 22

Author(s):

Christopher J. Levy ◽

Richard J. Puddephatt ◽

Jagadese J. Vittal

Keyword(s):

Oxidative Addition ◽

Synthesis And Characterization ◽

Halogen Effect

Oxidative Addition of Group 14 Element Hydrido Compounds to OsH2(η2-CH2CHEt)(CO)(PiPr3)2: Synthesis and Characterization of the First Trihydrido−Silyl, Trihydrido−Germyl, and Trihydrido−Stannyl Derivatives of Osmium(IV)

Inorganic Chemistry ◽

10.1021/ic9509591 ◽

1996 ◽

Vol 35 (5) ◽

pp. 1250-1256 ◽

Cited By ~ 26

Author(s):

María L. Buil ◽

Pablo Espinet ◽

Miguel A. Esteruelas ◽

Fernando J. Lahoz ◽

Agustí Lledós ◽

...

Keyword(s):

Oxidative Addition ◽

Synthesis And Characterization ◽

Group 14 ◽

Derivatives Of

Synthesis and characterization of rhodium(I) 2-methylcupferrate complexes and their kinetic behaviour in iodomethane oxidative addition

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2012.12.005 ◽

2013 ◽

Vol 726 ◽

pp. 14-20 ◽

Cited By ~ 4

Author(s):

Stefan Warsink ◽

Fanuel G. Fessha ◽

Walter Purcell ◽

Johan A. Venter

Keyword(s):

Oxidative Addition ◽

Synthesis And Characterization ◽

Kinetic Behaviour

Synthesis and Characterization of Methoxy-bridged Bis(silylene)tungsten Complexes

Journal of Scientific Research ◽

10.3329/jsr.v4i1.7890 ◽

2011 ◽

Vol 4 (1) ◽

pp. 109 ◽

Cited By ~ 1

Author(s):

R. Begum ◽

S. M. S. Islam

Keyword(s):

Elemental Analysis ◽

Oxidative Addition ◽

Metal Center ◽

Synthesis And Characterization ◽

29Si Nmr ◽

Mechanism Of Formation ◽

Tungsten Complexes ◽

Plausible Mechanism ◽

Silylene Complexes

Synthesis of two methoxy bridged bis(silylene) complexes (CpMe4)W(CO)2 {(Et2Si)••OMe••(SiMe2)}(3) and (CpMe)W(CO)2 {(Et2Si)••OMe••(SiMe2)}(4) have been synthesized. Both the compounds contain chiral tungsten center and formed via oxidative addition of an Si-H bond to a coordinatively unsaturated metal center. The complexes were characterized by 1H, 13C, 29Si NMR, IR and elemental analysis. A plausible mechanism of formation is also suggested.Keywords: Coordinatively unsaturated; Chiral tungsten; Oxidative addition.© 2012 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved.doi: http://dx.doi.org/10.3329/jsr.v4i1.7890J. Sci. Res. 4 (1), 109-118 (2012)

Double oxidative addition of CH bonds on a triruthenium cluster complex; synthesis and characterization of Ru3{μ-H2,η2,μ3-C(OEt)=C(H)}(CO)9 and Ru3{μ-H2,η2,μ3-C(OEt)N(Me)C(CH)}(CO)9

Journal of Organometallic Chemistry ◽

10.1016/0022-328x(87)80283-8 ◽

1987 ◽

Vol 330 (1-2) ◽

pp. 133-154 ◽

Cited By ~ 12

Author(s):

Craig M. Jensen ◽

Herbert D. Kaesz

Keyword(s):

Oxidative Addition ◽

Synthesis And Characterization ◽

Cluster Complex

Oxidative addition/reductive elimination of aldehydes and ketones at rhodium. Synthesis and characterization of cis-hydrido acyl complexes of rhodium(III)

Organometallics ◽

10.1021/om00154a032 ◽

1987 ◽

Vol 6 (11) ◽

pp. 2453-2455 ◽

Cited By ~ 15

Author(s):

Claudio. Bianchini ◽

Andrea. Meli ◽

Maurizio. Peruzzini ◽

Alberto. Vacca ◽

Fabrizio. Zanobini

Keyword(s):

Oxidative Addition ◽

Reductive Elimination ◽

Synthesis And Characterization ◽

Acyl Complexes ◽

Aldehydes And Ketones

Synthesis and characterization of Cp2Ti-containing organometallics via in situ oxidative-addition of ‘Cp2Ti’ intermediate.

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(01)01413-9 ◽

2002 ◽

Vol 648 (1-2) ◽

pp. 119-125 ◽

Cited By ~ 26

Author(s):

Li-Cheng Song ◽

Peng-Chong Liu ◽

Cong Han ◽

Qing-Mei Hu

Keyword(s):

Oxidative Addition ◽

Synthesis And Characterization

Synthesis and study of platinum silylene complexes of the type (R3P)2Pt=SiMes2 (Mes = 2,4,6-trimethylphenyl)

Canadian Journal of Chemistry ◽

10.1139/v03-018 ◽

2003 ◽

Vol 81 (11) ◽

pp. 1127-1136 ◽

Cited By ~ 25

Author(s):

Jay D Feldman ◽

Gregory P Mitchell ◽

Jörn-Oliver Nolte ◽

T Don Tilley

Keyword(s):

Oxidative Addition ◽

Reductive Elimination ◽

Synthesis And Characterization ◽

Silylene Complexes

The synthesis and characterization of neutral platinum silylene complexes (R3P)2Pt=SiMes2 (R = i-Pr (1) or cyclohexyl (2), Mes = 2,4,6-trimethylphenyl) is reported. The dimesitylsilylene ligand in 2 is displaced by a number of ligands including phosphines, alkenes, alkynes, and O2. Complex 2 reacts with ROH substrates (R = H, Me, Et) to give (Cy3P)2Pt and Mes2Si(OR)(H) and with H2 to give trans-(Cy3P)2Pt(H)SiHMes2 (3). Reaction of H2SiMes2 with (Cy3P)2Pt gave cis-(Cy3P)2Pt(H)SiHMes2 (4). EXSY NMR experiments of 4 reveal that exchange of silicon and platinum hydrides occurs via reductive elimination oxidative addition and not via a silylene intermediate.Key words: silylene, EXSY, platinum, hydride.