Synthesis and first use of pyridine-2,6-diylbis(pyrazine-2-ylmethanone) in metal cluster chemistry: a {MnIII3Na2} complex with an ideal trigonal bipyramidal geometry

2015 ◽  
Vol 44 (9) ◽  
pp. 4318-4327
Author(s):  
Dimosthenis P. Giannopoulos ◽  
Cody Wilson-Konderka ◽  
Kevin J. Gagnon ◽  
Simon J. Teat ◽  
Albert Escuer ◽  
...  
Keyword(s):  
Metal Cluster ◽  
Cluster Chemistry ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal

A new {Mn3Na2} compound with trigonal bipyramidal topology was obtained from a metal-assisted transformation of the ligand (pz)CO(py)CO(pz).

Theoretical aspects of metal cluster chemistry

1991 ◽  
Vol 63 (6) ◽  
pp. 807-812 ◽  
Author(s):  
D. M. P. Mingos
Keyword(s):  
Metal Cluster ◽  
Cluster Chemistry

ChemInform Abstract: The (Th12N6X41)13- Cluster: An Extension of Rare Earth Metal Cluster Chemistry.

ChemInform ◽  
2010 ◽  
Vol 27 (30) ◽  
pp. no-no
Author(s):  
T. P. BRAUN ◽  
A. SIMON ◽  
F. UENO ◽  
F. BOETTCHER
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Metal Cluster ◽  
Earth Metal ◽  
Cluster Chemistry

scholarly journals An orthorhombic polymorph of dichlorotris(pentafluorophenyl)phosphorane

2006 ◽  
Vol 62 (7) ◽  
pp. o2872-o2874
Author(s):  
Nicholas A. Barnes ◽  
Stephen M. Godfrey ◽  
Ruth T. A. Halton ◽  
Imrana Mushtaq ◽  
Robin G. Pritchard
Keyword(s):  
Crystal Packing ◽  
Trigonal Bipyramidal Geometry ◽  
Monoclinic Form ◽  
Trigonal Bipyramidal

An orthorhombic form of dichlorotris(pentafluorophenyl)phosphorane, C18Cl2F15P, has been obtained as the product of the reaction between PhSeCl and (C6F5)3P, and is a polymorph of the previously reported monoclinic form obtained from the reaction of (C6F5)3P with Cl2. The molecule displays nearly perfect trigonal–bipyramidal geometry, and features a number of intermolecular F...F contacts, which lead to fluorous domains in the crystal packing.

A hexagonal modification of catena-poly[[ethyldiphenyltin(IV)]-μ-2-chloroacetato-κ2 O:O′]

2007 ◽  
Vol 63 (3) ◽  
pp. m913-m914
Author(s):  
Mostafa M. Amini ◽  
Vajihe Alijani ◽  
Amirreza Azadmeher ◽  
Seik Weng Ng
Keyword(s):  
Coordination Polymer ◽  
Trigonal Bipyramidal Geometry ◽  
Trigonal Bipyramidal ◽  
Hexagonal Modification

In the title coordination polymer, [Sn(C2H5)(C6H5)2(C2H2ClO2)] n , the five-coordinate Sn atom shows an SnC3O2 trigonal–bipyramidal geometry, with O atoms in the axial positions.

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