Metal carbonyl cluster-based coordination polymers: diverse syntheses, versatile network structures, and special properties

This highlight surveys recent progress in groups 6–10 metal carbonyl cluster-based coordination polymers, focusing on diverse synthetic strategies, versatile structures, structural transformations, and semiconducting as well as magnetic properties.

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Synthesis and Structural Characterization of the {[Rh5(CO)14]−(H2N(CH2)4NH2)−[Rh5(CO)14])}2-and [Rh5(CO)13(H2N(CH2)2NH2)]-Anions (as [PPh4]+Salts): An Unprecedented Example of Carbonyl Substitution by Alkylamines in a Homoleptic Metal Carbonyl Cluster Anion

Inorganic Chemistry ◽

10.1021/ic0107936 ◽

2002 ◽

Vol 41 (1) ◽

pp. 76-85 ◽

Cited By ~ 10

Author(s):

Alessandro Fumagalli ◽

Maria Carlotta Malatesta ◽

Anna Tentori ◽

Diego Monti ◽

Piero Macchi ◽

...

Keyword(s):

Structural Characterization ◽

Metal Carbonyl ◽

Cluster Anion ◽

Carbonyl Cluster ◽

Carbonyl Substitution ◽

Metal Carbonyl Cluster

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Dynamic Rotation of Bridging Aryl Ligands in Unsaturated Metal Carbonyl Cluster Complexes

Organometallics ◽

10.1021/om400059c ◽

2013 ◽

Vol 32 (6) ◽

pp. 1587-1590 ◽

Cited By ~ 9

Author(s):

Richard D. Adams ◽

Vitaly Rassolov ◽

Qiang Zhang

Keyword(s):

Metal Carbonyl ◽

Carbonyl Cluster ◽

Cluster Complexes ◽

Metal Carbonyl Cluster ◽

Dynamic Rotation

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Systematic synthesis of hexanuclear clusters from pentanuclear clusters; crystal structure of [Os6H2(CO)19], a hexanuclear metal carbonyl cluster with a terminal hydride ligand

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39860000507 ◽

1986 ◽

pp. 507 ◽

Cited By ~ 6

Author(s):

Brian F. G. Johnson ◽

Rajesh Khattar ◽

Jack Lewis ◽

Mary McPartlin ◽

Jill Morris ◽

...

Keyword(s):

Crystal Structure ◽

Metal Carbonyl ◽

Carbonyl Cluster ◽

Hexanuclear Clusters ◽

Hydride Ligand ◽

Metal Carbonyl Cluster ◽

Systematic Synthesis

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Structure—Reactivity Relationships for Ionic Transition Metal Carbonyl Cluster Fragments

Gas Phase Inorganic Chemistry ◽

10.1007/978-1-4684-5529-8_4 ◽

1989 ◽

pp. 115-135 ◽

Cited By ~ 1

Author(s):

David H. Russell ◽

Donnajean Anderson Fredeen ◽

Ronald E. Tecklenburg

Keyword(s):

Transition Metal ◽

Metal Carbonyl ◽

Carbonyl Cluster ◽

Ionic Transition ◽

Metal Carbonyl Cluster

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Ion-molecule reaction chemistry of ionic transition-metal carbonyl cluster fragments. 1. Ligand-exchange reactions of chromium carbonyl (Cr2(CO)y+) ions

Journal of the American Chemical Society ◽

10.1021/ja00172a007 ◽

1990 ◽

Vol 112 (16) ◽

pp. 5953-5959 ◽

Cited By ~ 5

Author(s):

L. Sellers-Hann ◽

D. H. Russell

Keyword(s):

Transition Metal ◽

Ligand Exchange ◽

Metal Carbonyl ◽

Carbonyl Cluster ◽

Exchange Reactions ◽

Molecule Reaction ◽

Chromium Carbonyl ◽

Ionic Transition ◽

Metal Carbonyl Cluster

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Formation of ionic transition-metal carbonyl cluster fragments by ion-molecule reactions. 3. The heteronuclear systems

Journal of the American Chemical Society ◽

10.1021/ja00247a013 ◽

1987 ◽

Vol 109 (13) ◽

pp. 3903-3909 ◽

Cited By ~ 15

Author(s):

DonnaJean Anderson Fredeen ◽

David H. Russell

Keyword(s):

Transition Metal ◽

Metal Carbonyl ◽

Carbonyl Cluster ◽

Ion Molecule Reactions ◽

Ionic Transition ◽

Metal Carbonyl Cluster

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Metal Carbonyl Cluster Complexes as Electrocatalysts for PEM Fuel Cells

Nanostructured Materials for Next-Generation Energy Storage and Conversion ◽

10.1007/978-3-662-56364-9_4 ◽

2018 ◽

pp. 115-144

Author(s):

Jorge Uribe-Godínez

Keyword(s):

Fuel Cells ◽

Metal Carbonyl ◽

Pem Fuel Cells ◽

Carbonyl Cluster ◽

Cluster Complexes ◽

Metal Carbonyl Cluster

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Temperature-induced structural transformations accompanied by changes in magnetic properties of two copper coordination polymers

CrystEngComm ◽

10.1039/d0ce00391c ◽

2020 ◽

Vol 22 (20) ◽

pp. 3482-3488 ◽

Cited By ~ 1

Author(s):

Jing Tu ◽

Hongjuan Chen ◽

Hongju Tian ◽

Xianyong Yu ◽

Baishu Zheng ◽

...

Keyword(s):

Magnetic Properties ◽

Coordination Polymers ◽

Structural Transformations ◽

Organic Ligands ◽

Coordination Modes ◽

Copper Compounds ◽

Copper Coordination

Two ferromagnetic copper compounds have been synthesized under different temperature, which represented the rare example of structural transformations resulting from the coordination modes of organic ligands supported by magnetic results.

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