scholarly journals The effect of side-chain branch position on the thermal properties of poly(3-alkylthiophenes)

2020 ◽  
Vol 11 (2) ◽  
pp. 517-526 ◽  
Author(s):  
Zhiqiang Cao ◽  
Luke Galuska ◽  
Zhiyuan Qian ◽  
Song Zhang ◽  
Lifeng Huang ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Backbone Dynamics ◽  
Side Chain ◽  
Lower Side ◽  
Chain Branch

Branching closer to the backbone causes tighter packing in the side-chain direction and lower side chain and backbone dynamics.

scholarly journals Side-Chain to Main-Chain Hydrogen Bonding Controls the Intrinsic Backbone Dynamics of the Amyloid Precursor Protein Transmembrane Helix

2014 ◽  
Vol 106 (6) ◽  
pp. 1318-1326 ◽  
Author(s):  
Christina Scharnagl ◽  
Oxana Pester ◽  
Philipp Hornburg ◽  
Daniel Hornburg ◽  
Alexander Götz ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Amyloid Precursor Protein ◽  
Main Chain ◽  
Transmembrane Helix ◽  
Precursor Protein ◽  
Backbone Dynamics ◽  
Side Chain

Investigations of Thermal Properties of Some Polyesterimides with Polynaphthalene Rings in the Side Chain

1972 ◽  
pp. 197-203
Author(s):  
Z. Jedliński ◽  
D. Sek ◽  
U. Gaik
Keyword(s):  
Thermal Properties ◽  
Side Chain

Copolymers of long-side-chain di-n-alkyl itaconates or methyl n-alkyl itaconates with styrene: synthesis, characterization, and thermal properties

2012 ◽  
Vol 70 (1) ◽  
pp. 131-146 ◽  
Author(s):  
Francisco López-Carrasquero ◽  
Elizabeth Rangel-Rangel ◽  
Mayrin Cárdenas ◽  
Carlos Torres ◽  
Nahir Dugarte ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Side Chain

Side-chain type liquid-crystalline polyethers, 2 Effects of mesogenic moieties on the thermal properties and their self-assembly behaviour

1995 ◽  
Vol 196 (10) ◽  
pp. 3391-3414 ◽  
Author(s):  
Eiichi Akiyama ◽  
Miki Ohtomo ◽  
Yu Nagase ◽  
Naoyuki Koide
Keyword(s):  
Thermal Properties ◽  
Self Assembly ◽  
Liquid Crystalline ◽  
Side Chain ◽  
Chain Type

scholarly journals Variation of the Side Chain Branch Position Leads to Vastly Improved Molecular Weight and OPV Performance in 4,8-dialkoxybenzo[1,2-b:4,5-b′]dithiophene/2,1,3-benzothiadiazole Copolymers

2011 ◽  
Vol 2011 ◽  
pp. 1-10 ◽  
Author(s):  
Robert C. Coffin ◽  
Christopher M. MacNeill ◽  
Eric D. Peterson ◽  
Jeremy W. Ward ◽  
Jack W. Owen ◽  
...  
Keyword(s):  
Thin Film ◽  
Molecular Weight ◽  
Thin Film Transistor ◽  
Power Conversion ◽  
Hole Mobility ◽  
Side Chain ◽  
Side Chains ◽  
Absorption Profile ◽  
Polymer Backbone ◽  
Chain Branch

Through manipulation of the solubilizing side chains, we were able to dramatically improve the molecular weight(Mw)of 4,8-dialkoxybenzo[1,2-b:4,5-b′]dithiophene (BDT)/2,1,3-benzothiadiazole (BT) copolymers. When dodecyl side chains (P1) are employed at the 4- and 8-positions of the BDT unit, we obtain a chloroform-soluble copolymer fraction withMwof 6.3 kg/mol. Surprisingly, by moving to the commonly employed 2-ethylhexyl branch (P2),Mwdecreases to 3.4 kg/mol. This is despite numerous reports that this side chain increases solubility andMw. By moving the ethyl branch in one position relative to the polymer backbone (1-ethylhexyl,P3),Mwis dramatically increased to 68.8 kg/mol. As a result of thisMwincrease, the shape of the absorption profile is dramatically altered, withλmax= 637 nm compared with 598 nm forP1and 579 nm forP2. The hole mobility as determined by thin film transistor (TFT) measurements is improved from~1×10−6 cm2/Vs forP1andP2to7×10−4 cm2/Vs forP3, while solar cell power conversion efficiency in increased to2.91%forP3relative to0.31%and0.19%forP1andP2, respectively.

Synthesis and thermal properties of side chain-type liquid crystalline polyurethanes

1993 ◽  
Vol 14 (6) ◽  
pp. 1645-1654 ◽  
Author(s):  
Eiichi Akiyama ◽  
Naoyuki Koide
Keyword(s):  
Thermal Properties ◽  
Liquid Crystalline ◽  
Side Chain ◽  
Chain Type

Synthesis and thermal properties of side-chain liquid crystalline polyethers with racemic and chiral backbone

1994 ◽  
Vol 5 (4) ◽  
pp. 203-215 ◽  
Author(s):  
Daniel Taton ◽  
Alain Le Borgne ◽  
Nicolas Spassky ◽  
Claude Friedrich ◽  
Claudine Noël
Keyword(s):  
Thermal Properties ◽  
Liquid Crystalline ◽  
Side Chain

scholarly journals Side Chain and Backbone Dynamics of Phospholamban in Phospholipid Bilayers Utilizing2H and15N Solid-State NMR Spectroscopy†

Biochemistry ◽  
2007 ◽  
Vol 46 (42) ◽  
pp. 11695-11706 ◽  
Author(s):  
Shadi Abu-Baker ◽  
Jun-Xia Lu ◽  
Shidong Chu ◽  
Clarke C. Brinn ◽  
Christopher A. Makaroff ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Solid State Nmr ◽  
Phospholipid Bilayers ◽  
Backbone Dynamics ◽  
Side Chain ◽  
Solid State Nmr Spectroscopy
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