Substitution on a methyl group of an acetylacetonate ligand: synthesis and structural characterization of oxobis[6-(phenylamino)hexane-2,4-dionato-O,O′]vanadium(IV), VO(Phad)2

1996 ◽  
pp. 2113-2114 ◽  
Author(s):  
Deirdre I. Arnold ◽  
F. Albert Cotton ◽  
John H. Matonic ◽  
Carlos A. Murillo
Keyword(s):  
Structural Characterization ◽  
Methyl Group ◽  
Ligand Synthesis

A Methyl Group Bridging on Three Metal Atoms. Solid-State and Solution Structural Characterization of the [Re3(μ-H)3(μ3-CH3)(CO)9]-Anion

1999 ◽  
Vol 121 (10) ◽  
pp. 2307-2308 ◽  
Author(s):  
T. Beringhelli ◽  
G. D'Alfonso ◽  
M. Panigati ◽  
F. Porta ◽  
P. Mercandelli ◽  
...  
Keyword(s):  
Solid State ◽  
Structural Characterization ◽  
Methyl Group ◽  
Metal Atoms

Coordination Frameworks Containing the Pyrimidin-4-olate Ligand. Synthesis, Thermal, Magnetic, andab InitioXRPD Structural Characterization of Nickel and Zinc Derivatives

2004 ◽  
Vol 43 (2) ◽  
pp. 473-481 ◽  
Author(s):  
Elisa Barea ◽  
Jorge A. R. Navarro ◽  
Juan M. Salas ◽  
Norberto Masciocchi ◽  
Simona Galli ◽  
...  
Keyword(s):  
Structural Characterization ◽  
Ligand Synthesis ◽  
Coordination Frameworks

A chalcogen-stabilized cluster containing a s-trans-1,3-diene ligand: synthesis and structural characterization of {(CO)6Fe2Se2}2(μ-s-trans-C4H2)

1996 ◽  
Vol 506 (1-2) ◽  
pp. 307-312 ◽  
Author(s):  
Pradeep Mathu ◽  
Aswini K. Dash ◽  
Md.Munki Hossain ◽  
C.V.V. Satyanarayana ◽  
Babu Verghese
Keyword(s):  
Structural Characterization ◽  
Ligand Synthesis

scholarly journals 2-Mercapto-1-t-butylimidazolyl as a bridging ligand: Synthesis and structural characterization of nickel and palladium paddlewheel complexes

2009 ◽  
Vol 362 (12) ◽  
pp. 4609-4615 ◽  
Author(s):  
Keliang Pang ◽  
Joshua S. Figueroa ◽  
Ian A. Tonks ◽  
Wesley Sattler ◽  
Gerard Parkin
Keyword(s):  
Structural Characterization ◽  
Paddlewheel Complexes ◽  
Bridging Ligand ◽  
Ligand Synthesis

Structural characterization of protonated benzeneseleninic acid, the dihydroxyselenonium ion

2000 ◽  
Vol 56 (6) ◽  
pp. 1029-1034 ◽  
Author(s):  
Henning Osholm Sørensen ◽  
Nicolai Stuhr-Hansen ◽  
Lars Henriksen ◽  
Sine Larsen
Keyword(s):  
Hydrogen Bond ◽  
Chemical Shift ◽  
Structural Characterization ◽  
Strong Acid ◽  
Crystallization Behaviour ◽  
Methyl Group ◽  
Bond Lengths ◽  
Pyramidal Configuration

The structure of the dihydroxyphenylselenonium ion (C_{6}H_{7}O_{2}Se^{+}) has been determined in its benzenesulfonate (C_{6}H_{5}O_{3}Se^{-}) and p-toluenesulfonate (C_{7}H_{7}O_{3}S ^{-}) salts. Whereas the former salt is disordered, the latter less dense salt is well defined. This difference in crystallization behaviour is attributed to a C—H...O hydrogen bond involving the methyl group of the p-toluenesulfonate ion. The two salts display very similar hydrogen-bond arrangements and differ only with respect to the stacking of the phenyl groups. The dihydroxyselenonium ion is a strong acid with a pK value of −0.9 determined from the variation of the 77Se chemical shift. A comparison with the two deprotonated species reveals a systematic increase in the Se—O bond lengths and the pyramidal configuration around Se with the number of protons attached.

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