Homochiral three-dimensional noncentrosymmetric lanthanide coordination polymers directed by chiral linkers: syntheses, crystal structures, and optical properties

CrystEngComm ◽  
2021 ◽  
Author(s):  
Yunseung Kuk ◽  
Kang Min Ok

Crystals of six enantiomorphic lanthanide-organic coordination polymers, [Ln2((R,R)-TBA)2((R,R)-HTBA)2(H2O)2]·7H2O [Ln(R)] and Ln2((S,S)-TBA)2((S,S)- HTBA)2(H2O)2]·7H2O [Ln(S)] (Ln = La, Ce, and Pr; TBA = 1,3,5-triazin-2(1H)-one-4,6- bis(alanyl)), have been grown through solvothermal reactions. The...

CrystEngComm ◽  
2012 ◽  
Vol 14 (23) ◽  
pp. 8083 ◽  
Author(s):  
Li-Min Zhang ◽  
Da-Yi Deng ◽  
Guo Peng ◽  
Lin Sun ◽  
Li Liang ◽  
...  

CrystEngComm ◽  
2014 ◽  
Vol 16 (21) ◽  
pp. 4633-4640 ◽  
Author(s):  
Di-Chang Zhong ◽  
Wen-Guan Lu ◽  
Ji-Hua Deng

Two 3D cadmium(ii) coordination polymers have been prepared by controlling the pH values of the reaction mixture.


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