Homochiral three-dimensional noncentrosymmetric lanthanide coordination polymers directed by chiral linkers: syntheses, crystal structures, and optical properties
Keyword(s):
Crystals of six enantiomorphic lanthanide-organic coordination polymers, [Ln2((R,R)-TBA)2((R,R)-HTBA)2(H2O)2]·7H2O [Ln(R)] and Ln2((S,S)-TBA)2((S,S)- HTBA)2(H2O)2]·7H2O [Ln(S)] (Ln = La, Ce, and Pr; TBA = 1,3,5-triazin-2(1H)-one-4,6- bis(alanyl)), have been grown through solvothermal reactions. The...
2009 ◽
Vol 921
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pp. 126-131
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pp. 2097-2105
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pp. 1036-1041
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