Carbocyclic Pincer Carbene Complexes of Ruthenium: Syntheses and Reversible Hydrogenation

2021 ◽  
Author(s):  
Nicholas Wiedmaier ◽  
Hartmut Schubert ◽  
Hermann A Mayer ◽  
Lars Wesemann
Keyword(s):  
Carbene Complexes ◽  
Carbene Complex ◽  
Pincer Complex

The ruthenium carbene pincer complex 2 was synthesized treating the benzo annulated cycloheptatriene bisphosphine 1 with RuCl3. Addition of three equivalents of hydrogen to the carbocyclic carbene complex 2 was...

Cyclometallation reactions of a three-coordinate cobalt(i) complex bearing a nonsymmetric N-heterocyclic carbene ligand

2019 ◽  
Vol 48 (26) ◽  
pp. 9676-9683 ◽  
Author(s):  
Yafei Gao ◽  
Qi Chen ◽  
Xuebing Leng ◽  
Liang Deng
Keyword(s):  
Carbene Complexes ◽  
Organometallic Reagents ◽  
Carbene Complex

The reactions of a three-coordinate cobalt(i)–N-heterocyclic carbene complex with different organometallic reagents afford different cyclometallated cobalt–N-heterocyclic carbene complexes.

scholarly journals Catalytic Hydrogenation of α,β-Unsaturated Carboxylic Acid Derivatives Using copper(I)/N-Heterocyclic Carbene Complexes

2018 ◽  
Author(s):  
Birte Zimmermann ◽  
Johannes Teichert
Keyword(s):  
Carboxylic Acid ◽  
Catalytic Hydrogenation ◽  
Economic Transformation ◽  
Reducing Agent ◽  
Carbene Complexes ◽  
Carbene Complex ◽  
Unsaturated Carboxylic Acid

A simple and air-stable copper(I)/N-heterocyclic carbene complex enables the catalytic hydrogenation of hitherto unreactive enoates and enamides employing H2 as terminal reducing agent. This atom economic transformation replaces commonly employed hydrosilanes and can also be carried out in an asymmetric fashion.<br><br>

Donor functionalized ruthenium N-heterocyclic carbene complexes in alcohol oxidation reactions

2014 ◽  
Vol 43 (14) ◽  
pp. 5335-5342 ◽  
Author(s):  
Abbas Raja Naziruddin ◽  
Chun-Shiuan Zhuang ◽  
Wan-Jung Lin ◽  
Wen-Shu Hwang
Keyword(s):  
Alcohol Oxidation ◽  
Oxidation Reactions ◽  
Carbene Complexes ◽  
Coordination Modes ◽  
Pincer Complex ◽  
Oxidation Of Alcohols

Ruthenium chelates bearing N^C^O-donors in bidentate or pincer coordination modes have been prepared. The ruthenium pincer complex catalyses the oxidation of alcohols to the corresponding aldehydes with yields as high as 99%.

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