Oxidative Addition, Reduction and Reductive Coupling: The Versatile Reactivity of Subvalent Gallium Cations.

2021 ◽  
Author(s):  
Marcel Schorpp ◽  
Razan Tamim ◽  
Ingo Krossing
Keyword(s):  
Oxidative Addition ◽  
Reductive Coupling ◽  
Hydride Complex ◽  
Gallium Hydride

Intrigued by the successful oxidative addition of a P-H bond to univalent Ga[Al(ORF)4] giving the unprecedented dicationic gallium hydride complex [H-Ga(PPh3)3][Al(ORF)4]2 (ORF = OC(CF3)3), the oxidative addition of E-Cl containing...

An N-Heterocyclic Carbene/Iridium Hydride Complex from the Oxidative Addition of a Ferrocenyl-Bisimidazolium Salt: Implications for Synthesis

2004 ◽  
Vol 44 (3) ◽  
pp. 444-447 ◽  
Author(s):  
Mónica Viciano ◽  
Elena Mas-Marzá ◽  
Macarena Poyatos ◽  
Mercedes Sanaú ◽  
Robert H. Crabtree ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Hydride Complex

Arene C–H bond activation and methane formation by a methylplatinum(ii) complex: experimental and theoretical elucidation of the mechanism

2019 ◽  
Vol 43 (21) ◽  
pp. 8005-8014 ◽  
Author(s):  
Asma Nahaei ◽  
S. Masoud Nabavizadeh ◽  
Fatemeh Niroomand Hosseini ◽  
S. Jafar Hoseini ◽  
Mahdi M. Abu-Omar
Keyword(s):  
Bond Activation ◽  
Oxidative Addition ◽  
Methane Formation ◽  
Donor Atom ◽  
Computational Investigation ◽  
Hydride Complex

A combined experimental/computational investigation reveals that the cyclometalation of [PtMe2(DMSO)2], 1, by HC^N ligands proceeds via HC^N coordination through the N donor atom, oxidative addition of the arene C–H bond, and final dissociation of methane from a platinum hydride complex.

An N-Heterocyclic Carbene/Iridium Hydride Complex from the Oxidative Addition of a Ferrocenyl-Bisimidazolium Salt: Implications for Synthesis

2004 ◽  
Vol 117 (3) ◽  
pp. 448-451 ◽  
Author(s):  
Mónica Viciano ◽  
Elena Mas-Marzá ◽  
Macarena Poyatos ◽  
Mercedes Sanaú ◽  
Robert H. Crabtree ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Hydride Complex

Reductive Coupling of Six Carbon Monoxides by a Ditantalum Hydride Complex

2009 ◽  
Vol 131 (10) ◽  
pp. 3474-3475 ◽  
Author(s):  
Takahito Watanabe ◽  
Yutaka Ishida ◽  
Tsukasa Matsuo ◽  
Hiroyuki Kawaguchi
Keyword(s):  
Reductive Coupling ◽  
Hydride Complex

Oxidative Addition of Aryl Halides to Transient Anionic à-Aryl–Palladium(0) Intermediates—Application to Palladium-Catalyzed Reductive Coupling of Aryl Halides

1996 ◽  
Vol 2 (8) ◽  
pp. 957-966 ◽  
Author(s):  
Christian Amatore ◽  
Emmanuelle Carré ◽  
Anny Jutand ◽  
Hideo Tanaka ◽  
Qinghua Ren ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Aryl Halides ◽  
Reductive Coupling ◽  
Palladium Catalyzed

scholarly journals Paddle Ball Dynamics during Conversion of a Rh–Methyl Hydride Complex to a Rh–Methane σ-Complex through Reductive Coupling

2019 ◽  
Vol 38 (10) ◽  
pp. 2280-2287 ◽  
Author(s):  
Ryan Carlsen ◽  
Jordan R. Jenkins ◽  
Tsung-Chiang Johnny Huang ◽  
Samuel L. Pugh ◽  
Daniel H. Ess
Keyword(s):  
Reductive Coupling ◽  
Hydride Complex
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