Wavelength dependent photochemistry of BODIPY–phenols and their applications in the fluorescent labeling of proteins

2021 ◽  
Author(s):  
Katarina Zlatić ◽  
Matej Cindrić ◽  
Ivana Antol ◽  
Lidija Uzelac ◽  
Branka Mihaljević ◽  
...  
Keyword(s):  
Fluorescent Labeling ◽  
Excited Singlet ◽  
Photochemical Reactivity ◽  
Singlet States ◽  
Excited Singlet States

The molecules undergo wavelength dependent photochemistry, since photodeamination to QMs takes place only upon excitation to higher excited singlet states, showing unusual anti-Kasha photochemical reactivity.

Quasiparticle Excitations in Polyenes and Polyacetylene

1987 ◽  
Vol 109 ◽  
Author(s):  
Paul Tavan ◽  
Klaus Schulten
Keyword(s):  
Dispersion Relations ◽  
Excited Singlet ◽  
Quasi Particle ◽  
Double Excitation ◽  
Singlet States ◽  
Excited Singlet States ◽  
Electron Excitations ◽  
Quasiparticle Excitations

ABSTRACTWe apply the Pariser-Parr-Pople Hamiltonian to study many-electron excitations in polyenes and polyacetylene. The excited singlet states of polyenes, calculated by a multireference double excitation expansion, are classified as quasi-particle excitations, namely as triplet-triplet magnons and particle-hole excitons. From finite polyene spectra we derive approximate dispersion relations for these quasi-particles in the infinite polyene, i.e. polyacetylene.

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