Highly photoluminescent poly(norbornene)s carrying platinum-acetylide complex moieties in the side chain: evaluation of oxygen sensing and TTA–UC

Norbornene Derivatives

Ring-opening metathesis polymerization (ROMP) of norbornene derivatives is useful for preparing thermally stable and transparent polymeric materials with good moldability. This study deals with ROMP of norbornene monomer 1 bearing...

Synthesis of side chain liquid crystal polymers by living ring-opening metathesis polymerization. 4. Synthesis of AB block copolymers containing amorphous and side chain liquid crystal blocks

Macromolecules ◽

10.1021/ma00058a030 ◽

1993 ◽

Vol 26 (6) ◽

pp. 1387-1392 ◽

Cited By ~ 47

Author(s):

Zen Komiya ◽

Richard R. Schrock

Keyword(s):

Liquid Crystal ◽

Block Copolymers ◽

Ring Opening ◽

Side Chain ◽

Liquid Crystal Polymers ◽

Metathesis Polymerization

Alternating Ring-Opening Metathesis Polymerization (AROMP) of Hydrophobic and Hydrophilic Monomers Provides Oligomers with Side-Chain Sequence Control

Macromolecules ◽

10.1021/acs.macromol.8b00562 ◽

2018 ◽

Vol 51 (11) ◽

pp. 3932-3940 ◽

Cited By ~ 15

Author(s):

Guofang Li ◽

Nicole S. Sampson

Keyword(s):

Ring Opening ◽

Side Chain ◽

Chain Sequence ◽

Hydrophilic Monomers

Cationic tungsten imido alkylidene N-heterocyclic carbene complexes for stereospecific ring-opening metathesis polymerization of norbornene derivatives

Polymer Chemistry ◽

10.1039/d1py01158h ◽

2021 ◽

Author(s):

Janis V. Musso ◽

Mathis Benedikter ◽

Paul Gebel ◽

Vincent Gramm ◽

Dongren Wang ◽

...

Keyword(s):

Ring Opening ◽

Carbene Complexes ◽

Norbornene Derivatives

Cationic W alkylidene N-heterocyclic carbene complexes allow for the stereospecific ring-opening metathesis polymerization of norbornenes with high trans-iso- and high cis-syndiospecificity, respectively.

Regio- and stereoselective ring-opening metathesis polymerization of 3-ferrocenyl substituted cyclooctenes and copolymerization with norbornene derivatives

European Polymer Journal ◽

10.1016/j.eurpolymj.2020.109472 ◽

2020 ◽

Vol 124 ◽

pp. 109472

Author(s):

Feilong Liu ◽

Nannan Xu ◽

Li Ling ◽

Jianfeng Hu ◽

Hao Zhang

Keyword(s):

Ring Opening ◽

Norbornene Derivatives

Application of olefin metathesis in the synthesis of functionalized polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials

Beilstein Journal of Organic Chemistry ◽

10.3762/bjoc.15.28 ◽

2019 ◽

Vol 15 ◽

pp. 310-332 ◽

Cited By ~ 5

Author(s):

Patrycja Żak ◽

Cezary Pietraszuk

Keyword(s):

Olefin Metathesis ◽

Ring Opening ◽

Polymeric Materials ◽

Acyclic Diene Metathesis ◽

Polyhedral Oligomeric Silsesquioxanes ◽

Cross Metathesis ◽

Terminal Olefins ◽

Synthesized Materials

This mini-review summarizes the applications of olefin metathesis in synthesis and functionalization of polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials. Three types of processes, i.e., cross metathesis (CM) of vinyl-substituted POSS with terminal olefins, acyclic diene metathesis (ADMET) copolymerization of divinyl-substituted POSS with α,ω-dienes and ring-opening metathesis polymerization (ROMP) of POSS-substituted norbornene (or other ROMP susceptible cycloolefins) are discussed. Emphasis was put on the synthetic and catalytic aspects rather than on the properties and applications of synthesized materials.