Synthesis and reactivity of trinuclear complexes of platinum containing the single bridging ligand SC4H8. Molecular structure of [NBu4]2[trans-PtCl2{(µ-SC4H8)Pt(C6F5)3}2]

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9890001011 ◽

1989 ◽

pp. 1011-1016 ◽

Author(s):

Rafaei Usón ◽

Juan Forniés ◽

Milagros Tomás ◽

Irene Ara

Keyword(s):

Molecular Structure ◽

Bridging Ligand ◽

Trinuclear Complexes

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Synthesis and characterisation of homo- and hetero-trinuclear complexes containing the triply-bridging diphenylthiophosphinito [µ3-SPPh2]–ligand: molecular structure of [Pd3(µ3-SPPh2)2(C6F5)2(C6H4CH2NMe2-2)(PPh3)2]ClO4·0.8CH2Cl2

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9950002805 ◽

1995 ◽

pp. 2805-2811 ◽

Author(s):

Juan Forniés ◽

Francisco Martinez ◽

Rafael Navarro ◽

Esteban P. Urriolabeitia ◽

Alan J. Welch

Keyword(s):

Molecular Structure ◽

Trinuclear Complexes

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Heterobi- and -trinuclear Complexes with an Amino(ethynyl)carbene as Bridging Ligand

Zeitschrift für anorganische und allgemeine Chemie ◽

10.1002/zaac.200400162 ◽

2004 ◽

Vol 630 (12) ◽

pp. 1863-1868 ◽

Author(s):

Helmut Fischer ◽

Cornelia Hartbaum ◽

Christiane Wespel ◽

Markus Dede

Keyword(s):

Bridging Ligand ◽

Trinuclear Complexes

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Complexed bridging ligand, [M(bpca)2] (M = Mn(II) or Fe(II); Hbpca = bis(2-pyridylcarbonyl)amine), as a building block for linear trinuclear complexes

Journal of the Chemical Society Dalton Transactions ◽

10.1039/a806618c ◽

1998 ◽

pp. 3351-3352 ◽

Author(s):

Takashi Kajiwara ◽

Tasuku Ito

Keyword(s):

Building Block ◽

Bridging Ligand ◽

Trinuclear Complexes

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ChemInform Abstract: CHARACTERIZATION OF CHELATING BIS((DIPHENYLPHOSPHINO)METHYL)PHENYLPHOSPHINE AS A BRIDGING LIGAND IN BI- AND TRINUCLEAR COMPLEXES

Chemischer Informationsdienst ◽

10.1002/chin.198345315 ◽

1983 ◽

Vol 14 (45) ◽

Author(s):

R. R. GUIMERANS ◽

M. M. OLMSTEAD ◽

A. L. BALCH

Keyword(s):

Abstract Characterization ◽

Bridging Ligand ◽

Trinuclear Complexes

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Trinuclear complexes of 1,3,5,7-tetraketonates. Synthesis, molecular structure, absorption spectra, and electrochemistry of several bis[1,7-diphenyl-1,3,5,7-heptanetetronato(3-)]bis[dioxouranium(VI)]metal(II)-4-pyridine complexes

Inorganic Chemistry ◽

10.1021/ic00186a031 ◽

1984 ◽

Vol 23 (18) ◽

pp. 2867-2874 ◽

Author(s):

R. L. Lintvedt ◽

B. A. Schoenfelner ◽

C. Ceccarelli ◽

M. D. Glick

Keyword(s):

Molecular Structure ◽

Absorption Spectra ◽

Pyridine Complexes ◽

Trinuclear Complexes

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Syntheses, Structures, and Properties of Trinuclear Complexes [M(bpca)2{M‘(hfac)2}2], Constructed with the Complexed Bridging Ligand [M(bpca)2] [M, M‘ = Ni(II), Mn(II); Cu(II), Mn(II); Fe(II), Mn(II); Ni(II), Fe(II); and Fe(II), Fe(II); Hbpca = Bis(2-pyridylcarbonyl)amine, Hhfac = Hexafluoroacetylacetone]

Inorganic Chemistry ◽

10.1021/ic010731f ◽

2002 ◽

Vol 41 (3) ◽

pp. 507-512 ◽

Author(s):

Asako Kamiyama ◽

Tomoko Noguchi ◽

Takashi Kajiwara ◽

Tasuku Ito

Keyword(s):

Bridging Ligand ◽

Trinuclear Complexes ◽

Structures And Properties

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Characterization of chelating bis[(diphenylphosphino)methyl]phenylphosphine as a bridging ligand in bi- and trinuclear complexes

Inorganic Chemistry ◽

10.1021/ic00158a001 ◽

1983 ◽

Vol 22 (16) ◽

pp. 2223-2224 ◽

Author(s):

Rosalvina R. Guimerans ◽

Marilyn M. Olmstead ◽

Alan L. Balch

Keyword(s):

Bridging Ligand ◽

Trinuclear Complexes

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Magnetic Properties of a Series of Trinuclear Complexes (CuL)2Mn·xB (L Representing the Deprotonated Form ofN-(4-Methyl-6-oxo-3-azahept-4-enyl)oxamic Acid and B Representing Respectively H2O (x= 5, 4.5, 3, 1), (CH3)2SO (x= 2), and C5H5N (x= 4)). Crystal and Molecular Structure of (CuL)2Mn·2(CH3)2SO

Inorganic Chemistry ◽

10.1021/ic970372h ◽

1997 ◽

Vol 36 (21) ◽

pp. 4641-4646 ◽

Author(s):

Jean-Pierre Costes ◽

Jean-Pierre Laurent ◽

Jose Maria Moreno Sanchez ◽

Jose Suarez Varela ◽

Markku Ahlgren ◽

...

Keyword(s):

Molecular Structure ◽

Magnetic Properties ◽

Crystal And Molecular Structure ◽

Deprotonated Form ◽

Trinuclear Complexes

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Dinuclear zirconium complexes with Me2Si(C5H4)2as bridging ligand. Molecular structure of [{Zr(η5-C5H3-But2)Me}2(µ-O){µ-Me2Si(C5H4)2}]

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9950000231 ◽

1995 ◽

pp. 231-236 ◽

Author(s):

Gemma Ciruelo ◽

Tomás Cuenca ◽

Pilar Gómez-Sal ◽

Avelino Martín ◽

Pascual Royo

Keyword(s):

Molecular Structure ◽

Bridging Ligand ◽

Zirconium Complexes

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Das Dimethylphosphanomethanid-Ion als Brückenligand - Struktur von μ-Dimethylphosphido, μ-Dimethylphosphanomethanidotetrakis(trimethylphosphan)dicobalt / The Dimethylphosphanomethanide Ion as a Bridging Ligand - Structure of μ-Dimethylphosphido, μ-Dimethylphosphanomethanidotetrakis(trimethylphosphane)dicobalt

Zeitschrift für Naturforschung B ◽

10.1515/znb-1979-1009 ◽

1979 ◽

Vol 34 (10) ◽

pp. 1391-1397 ◽

Author(s):

Hans-Friedrich Klein ◽

Josef Wenninger ◽

Ulrich Schubert

Keyword(s):

Molecular Structure ◽

Carbon Monoxide ◽

Title Compound ◽

Binuclear Complex ◽

Heterocyclic System ◽

Cleavage Reaction ◽

Bridging Ligand ◽

Ligand Structure

Dinitrogen cobaltates [(Me3P)3CoN2]2Mg(THF)4 and KN2Co(PMe3)3 react with CoCl(PMe3)3 or NiCl2(PMe3)2 to give a novel binuclear complex (Me3P)2Co(CH2PMe2)(PMe2)Co(PMe3)2 of unusual properties. Carbon monoxide produces Me3P(CO)2Co(CH2PMe2)(PMe2)Co(CO)2PMe3 but does not insert into the Co-C bond. A cleavage reaction by trimethylphosphite yields (Me3P)2[(MeO)3P]2CoP(O)(OMe)2. The molecular structure of the title compound reveals a novel heterocyclic system Co2P2C containing a CH2 group bent out of the Co2P2 plane (d(Co = Co) = 242.8(2) pm). The bond distances (d(P = C) = 171 pm, d(Co-C) = 209 pm) and angles (PCCo) = 88° suggest a type of bonding which is best described as a P-metallated phosphorane coordinated to the second Co atom via its ylide function.

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