A Photocatalyst-Free, SET-Mediated Photochemical Approach for the Synthesis of Dumbbell-Like Amine-Functionalized Bis-C60 Fullerene through C–C Bond Formation
Keyword(s):
A novel method for the synthesis of dumbbell-like amine-functionalized bis-C60 fullerene from simple bis-α-silyl tertiary benzyl amines and C60 fullerene is described. The photoreactions between bis-α-silyl tertiary benzyl amines and C60 furnished single-bonded bis-aminomethyl-1,2-dihyrofullerenes and double-bonded 1,2,5-trisubstituted bis-fulleropyrrolidines through 1,3-dipolar cycloaddition reactions of azomethine ylides under mild conditions.
2006 ◽
Vol 47
(29)
◽
pp. 5139-5142
◽
Keyword(s):
2017 ◽
Vol 53
(12)
◽
pp. 1315-1323
◽
2008 ◽
Vol 47
(32)
◽
pp. 6055-6058
◽