Asymmetric 1,2- and 1,3-Inductions and Solvent Dependence Found in Chelate-Controlled Additions of Grignard Reagents and Cuprates to Chiral β-Formyl Esters. Stereoselective Synthesis of γ-Lactones

The stereoselective synthesis of C3-substituted morpholine derivatives has been achieved through a two-step process involving diastereoselective addition of a Grignard reagent to a sulfinyl imine, followed by cyclization.

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Stereoselective Synthesis of Optically Active Diethanolamines Utilizing Diastereoselective Reaction of 1,3-Oxazolidines with Grignard Reagents

Heterocycles ◽

10.3987/com-95-7116 ◽

1995 ◽

Vol 41 (9) ◽

pp. 2007 ◽

Cited By ~ 8

Author(s):

Kimio Higashiyama ◽

Katuyuki Nakagawa ◽

Hiroshi Takahashi

Keyword(s):

Stereoselective Synthesis ◽

Optically Active ◽

Grignard Reagents ◽

Diastereoselective Reaction

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Stereoselective Synthesis of trans-Olefins by the Copper-Mediated SN2′ Reaction of Vinyl Oxazines with Grignard Reagents. Asymmetric Synthesis of D-threo-Sphingosines.

ChemInform ◽

10.1002/chin.200729177 ◽

2007 ◽

Vol 38 (29) ◽

Author(s):

Om V. Singh ◽

Hyunsoo Han

Keyword(s):

Asymmetric Synthesis ◽

Stereoselective Synthesis ◽

Grignard Reagents ◽

Sn2 Reaction

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First stereoselective synthesis of enantiomerically pure telluronium salts by the reaction of chiral halooxatelluranes with Grignard reagents

Tetrahedron Asymmetry ◽

10.1016/s0957-4166(97)00459-x ◽

1997 ◽

Vol 8 (20) ◽

pp. 3357-3361 ◽

Cited By ~ 11

Author(s):

Jian Zhang ◽

Shinichi Saito ◽

Toru Koizumi

Keyword(s):

Stereoselective Synthesis ◽

Grignard Reagents ◽

Enantiomerically Pure

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ChemInform Abstract: Stereoselective Synthesis of Optically Active Diethanolamines Utilizing a Diastereoselective Reaction of 1,3-Oxazolidines with Grignard Reagents.

ChemInform ◽

10.1002/chin.199552084 ◽

2010 ◽

Vol 26 (52) ◽

pp. no-no

Author(s):

K. HIGASHIYAMA ◽

K. NAKAGAWA ◽

H. TAKAHASHI

Keyword(s):

Stereoselective Synthesis ◽

Optically Active ◽

Grignard Reagents ◽

Diastereoselective Reaction

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A stereoselective synthesis of trisubstituted alkenes. Part 1. Nickel-catalysed coupling of Grignard reagents with 5-alkyl-2,3-dihydrofurans

Journal of the Chemical Society Perkin Transactions 1 ◽

10.1039/p19920003419 ◽

1992 ◽

pp. 3419-3429 ◽

Cited By ~ 32

Author(s):

Philip J. Kocieński ◽

Martin Pritchard ◽

Sjoerd N. Wadman ◽

Richard J. Whitby ◽

Clive L. Yeates

Keyword(s):

Stereoselective Synthesis ◽

Grignard Reagents ◽

Trisubstituted Alkenes

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A stereoselective synthesis of trisubstituted alkenes. Part 2. The nickel-catalysed coupling of Grignard reagents with 6-alkyl-3,4-dihydro-2H-pyrans and acyclic enol ethers

Journal of the Chemical Society Perkin Transactions 1 ◽

10.1039/p19920003431 ◽

1992 ◽

pp. 3431-3438 ◽

Cited By ~ 13

Author(s):

Philip A. Ashworth ◽

Nicholas J. Dixon ◽

Philip J. Kocieński ◽

Sjoerd N. Wadman

Keyword(s):

Stereoselective Synthesis ◽

Grignard Reagents ◽

Enol Ethers ◽

Trisubstituted Alkenes

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ChemInform Abstract: Highly Stereoselective Synthesis of 6-Perfluoroalkyl-6-fluoroalka-2,3,5-(Z)-trienols Through Carbometallation-Elimination of 5-Perfluoroalkyl-Substituted 4(E)-Alken-2-ynols with Grignard Reagents.

ChemInform ◽

10.1002/chin.201009054 ◽

2010 ◽

Vol 41 (9) ◽

Author(s):

Zhichao Ma ◽

Rong Zeng ◽

Yihua Yu ◽

Shengming Ma

Keyword(s):

Stereoselective Synthesis ◽

Grignard Reagents

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