Carbenes Generated from Transition-Metal-Catalyzed Decomposition of Diazo Compounds

2004 ◽  
pp. 1
Author(s):  
V. Aggarwal ◽  
J. Richardson
Keyword(s):  
Transition Metal ◽  
Diazo Compounds ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Transition-Metal-Catalyzed Cross-Coupling with Non-Diazo Carbene Precursors

Synlett ◽  
2018 ◽  
Vol 30 (05) ◽  
pp. 542-551 ◽  
Author(s):  
Jianbo Wang ◽  
Kang Wang
Keyword(s):  
Transition Metal ◽  
Cross Coupling ◽  
Diazo Compounds ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Carbon Carbon Bond ◽  
Palladium Catalyzed ◽  
Fischer Carbenes ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Transition-metal-catalyzed cross-coupling reactions through metal carbene migratory insertion have emerged as powerful methodology for carbon–carbon bond constructions. Typically, diazo compounds (or in situ generated diazo compounds from N-tosylhydrazones) have been employed as the metal carbene precursors for this type of cross-coupling reactions. Recently, cross-coupling reactions employing non-diazo carbene precursors, such as conjugated ene-yne-ketones, allenyl ketones, alkynes, cyclopropenes, and Cr(0) Fischer carbenes, have been developed. This account will summarize our efforts in the development of transition-metal-catalyzed cross-coupling reactions with these non-diazo carbene precursors.1 Introduction2 Cross-Coupling with Ene-yne-ketones, Allenyl Ketones, and Alkynes3 Cross-Coupling Involving Ring-Opening of Cyclopropenes4 Palladium-Catalyzed Cross-Coupling with Chromium(0) Fischer Carbenes5 Conclusion

scholarly journals Progress in Diazo Compounds Mediated Transition-Metal-Catalyzed C—H Alkylation

2016 ◽  
Vol 36 (5) ◽  
pp. 889 ◽  
Author(s):  
Liang Wang ◽  
Zhana Li ◽  
Kang Wan ◽  
Xinga Qu ◽  
Siqian Hu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Diazo Compounds ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed
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