Supramolecular main-chain liquid crystalline polymers and networks with competitive hydrogen bonding: flexible bis-cinnamic acids as hydrogen bond donors in thermoreversible networks and polymers

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Inclusion of non-mesogenic pendant segments, such as alkyl, PEG and fluoroalkyl, at periodic intervals along the backbone of main-chain LCPs, that contain flexible spacers, provides an interesting alternative to control the mesophase structure and the layer periodicity.


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