Synthesis, crystal structure and Hirshfeld surface analysis of (4-methylphenyl)[1-(pentafluorophenyl)-5-(trifluoromethyl)-1H-1,2,3-triazol-4-yl]methanone
2021 ◽
Vol 77
(11)
◽
Keyword(s):
The title compound, C17H7F8N3O, was obtained via the reaction of 1-azido-2,3,4,5,6-pentafluorobenzene with 4,4,4-trifluoro-1-(p-tolyl)butane-1,3-dione using triethylamine as a base catalyst and solvent. The dihedral angles between the pentafluorophenyl (A), triazole (B) and p-tolyl (C) rings are A/B = 62.3 (2), B/C = 43.9 (3) and A/C = 19.1 (3)°. In the crystal, the molecules are linked by C—H...F and C—H...O hydrogen bonds as well as by aromatic π–π stacking interactions into a three-dimensional network. To further analyse the intermolecular interactions, a Hirshfeld surface analysis was performed.
2018 ◽
Vol 74
(4)
◽
pp. 441-444
◽
2021 ◽
Vol 77
(8)
◽
pp. 814-818
2019 ◽
Vol 75
(10)
◽
pp. 1544-1547
◽
2016 ◽
Vol 72
(5)
◽
pp. 716-719
◽
2019 ◽
Vol 75
(6)
◽
pp. 717-720
2017 ◽
Vol 73
(8)
◽
pp. 1197-1201
2019 ◽
Vol 75
(2)
◽
pp. 228-232
2021 ◽
Vol 77
(4)
◽
pp. 346-350
2019 ◽
Vol 75
(9)
◽
pp. 1331-1335
2019 ◽
Vol 75
(11)
◽
pp. 1734-1737
◽