scholarly journals (E)-1-(2-Hydroxy-6-methoxyphenyl)-3-(2-methoxynaphthalen-1-yl)prop-2-en-1-one

IUCrData ◽  
2019 ◽  
Vol 4 (9) ◽  
Author(s):  
Jiha Sung
Keyword(s):  
Hydrogen Bond ◽  
Benzene Ring ◽  
Dihedral Angle ◽  
Title Compound ◽  
Methoxy Group ◽  
Ring System ◽  
Naphthalene Ring ◽  
Compound C ◽  
Phenol Ring ◽  
Ring Motif

In the title compound, C21H18O4, the dihedral angle between the naphthelene ring system (r.m.s. deviation = 0.014 Å) and the benzene ring is 9.68 (1)°. The C atom of the methoxy group of the naphthalene ring system is almost coplanar with the ring [C—O—C—C = −2.0 (3)°], whereas the C atom of the methoxy group of the phenol ring is slightly twisted [C—O—C—C = 6.2 (3)°]. An intramolecular O—H...O hydrogen bond generates an S(6) ring motif.

scholarly journals 2-Hydroxy-N′-[2-(6-methoxynaphthalen-2-yl)propanoyl]benzohydrazide

2012 ◽  
Vol 68 (4) ◽  
pp. o1251-o1252
Author(s):  
Shaaban Kamel Mohamed ◽  
Peter N. Horton ◽  
Mehmet Akkurt ◽  
Mustafa R. Albayati ◽  
Herman Potgeiter
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Benzene Ring ◽  
Dihedral Angle ◽  
Torsion Angle ◽  
Title Compound ◽  
Ring System ◽  
Naphthalene Ring ◽  
Compound C ◽  
Ring Motif

In the title compound, C21H20N2O4, the naphthalene ring system makes a dihedral angle of 84.5 (3)° with the benzene ring, and the –C(=O)–N(H)–N(H)–C(=O)– torsion angle is 70.7 (7)°, so that the molecule is twisted. AnS(6) ring motif is formedviaan intramolecular O—H...O hydrogen bond. In the crystal, molecules are linked by N—H...O and C–H...O hydrogen bonds into supramolecular layers in theabplane.

scholarly journals 1-{(Z)-[2-Methoxy-5-(trifluoromethyl)anilino]methylidene}naphthalen-2(1H)-one

2013 ◽  
Vol 69 (2) ◽  
pp. o163-o163
Author(s):  
Hakan Kargılı ◽  
Ayşen Alaman Ağar ◽  
Gökhan Alpaslan ◽  
Orhan Büyükgüngör ◽  
Ahmet Erdönmez
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Benzene Ring ◽  
Dihedral Angle ◽  
Title Compound ◽  
Tautomeric Form ◽  
Ring System ◽  
Trifluoromethyl Group ◽  
Naphthalene Ring ◽  
Compound C

The title compound, C19H14F3NO2, crystallizes in the keto–amine tautomeric form, with a strong intramolecular N—H...O hydrogen bond. The molecule is almost planar; the dihedral angle between the naphthalene ring system and the benzene ring is 4.60 (7)°. In the crystal, molecules are linked into chains along thecaxis by C—H...O hydrogen bonds. The F atoms of the trifluoromethyl group are disordered over two positions with refined site occupancies of 0.668 (9) and 0.332 (9).

scholarly journals Crystal structure of 1-{(E)-[(3,4-dichlorophenyl)imino]methyl}naphthalen-2-ol

2015 ◽  
Vol 71 (9) ◽  
pp. o696-o696
Author(s):  
Muhammad Nawaz Tahir ◽  
Muhammad Anwar-ul-Haq ◽  
Hazoor Ahmad Shad
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Benzene Ring ◽  
Dihedral Angle ◽  
Torsion Angle ◽  
Title Compound ◽  
Ring System ◽  
Naphthalene Ring ◽  
Compound C

In the title compound, C17H11Cl2NO, the dihedral angle between the planes of the naphthalene ring system and the benzene ring is 28.88 (11)°. The main twist in the molecule occurs about the N—Cb(b = benzene ring) bond, as indicated by the C=N—Cb—Cbtorsion angle of 31.0 (4)°. An intramolecular O—H...N hydrogen bond closes anS(6) ring. In the crystal, inversion dimers linked by pairs of very weak C—H...O interactions generateR22(16) loops.

2-(1-Naphthyliminomethyl)phenol

2006 ◽  
Vol 62 (5) ◽  
pp. o1932-o1933
Author(s):  
Kui Cheng ◽  
Hai-Liang Zhu ◽  
Jing-Jing Liu ◽  
Meng Gao ◽  
Jun-He Zeng
Keyword(s):  
Hydrogen Bond ◽  
Dihedral Angle ◽  
Title Compound ◽  
Ring System ◽  
Naphthalene Ring ◽  
Compound C ◽  
Phenol Ring

In the molecule of the title compound, C17H13NO, the naphthalene ring system is essentially planar. A strong intramolecular O—H...N hydrogen bond results in the formation of a pseudo-six-membered planar ring, which makes a dihedral angle of 2.85 (5)° with the phenol ring.

scholarly journals The crystal structure of 2-[5-(dimethylamino)naphthalene-1-sulfonamido]phenyl 5-(dimethylamino)naphthalene-1-sulfonate

2015 ◽  
Vol 71 (10) ◽  
pp. o721-o722 ◽  
Author(s):  
Kittipong Chainok ◽  
Tanwawan Duangthongyou ◽  
Thawatchai Tuntulani ◽  
Apinya Chuenka ◽  
Boontana Wannalerse
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Benzene Ring ◽  
Dihedral Angle ◽  
Title Compound ◽  
Ring System ◽  
Naphthalene Ring ◽  
Twofold Axis ◽  
Compound C

The complete molecule of the title compound, C30H29N3O5S2, is generated by a crystallographic twofold axis: the O atom and NH group attached to the central benzene ring are statistically disordered. The dihedral angle between the naphthalene ring system and the central benzene ring is 52.99 (6)°, while the pendant naphthalene ring systems subtend a dihedral angle of 68.17 (4)°. An intramolecular C—H...O hydrogen bond closes anS(6) ring. In the crystal, the molecules are linked by weak C—H...O hydrogen bonds.

scholarly journals Crystal structure of 1-[(Z)-2-phenylhydrazin-1-ylidene]naphthalen-2(1H)-one

2015 ◽  
Vol 71 (5) ◽  
pp. o303-o303
Author(s):  
Ali Benosmane ◽  
Mohamed Amine Benaouida ◽  
Assia Mili ◽  
Abdelkader Bouchoul ◽  
Hocine Merazig
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Carbonyl Group ◽  
Benzene Ring ◽  
Dihedral Angle ◽  
Title Compound ◽  
Ring System ◽  
Imino Group ◽  
Compound C ◽  
Supramolecular Chains

In the title compound, C16H12N2O, the dihedral angle between the planes of the benzene ring and naphthalenone ring system is 1.89 (8)°; an intramolecular N—H...O hydrogen bond occurs between the imino group and the carbonyl group. In the crystal, molecules are linked by weak C—H...π interactions into supramolecular chains propagating along the [01-1] direction.

scholarly journals 2-(2,3-Dimethylanilino)benzohydrazide

2012 ◽  
Vol 68 (8) ◽  
pp. o2527-o2528 ◽  
Author(s):  
Hoong-Kun Fun ◽  
Tze Shyang Chia ◽  
Tilal Elsaman ◽  
Mohamed I. Attia ◽  
Hatem A. Abdel-Aziz
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Benzene Ring ◽  
Dihedral Angle ◽  
Title Compound ◽  
Crystal Packing ◽  
Compound C ◽  
Benzene Rings ◽  
Common Plane ◽  
Ring Motif

In the title compound, C15H17N3O, the dihedral angle between the benzene rings is 58.05 (9)°. The non-H atoms of the hydrazide group lie in a common plane (r.m.s. deviation = 0.0006 Å) and are close to coplanar with their attached benzene ring [dihedral angle = 8.02 (9)°]. An intramolecular N—H...O hydrogen bond generates anS(6) ring motif in the molecule, and a short intramolecular contact (H...H = 1.88 Å) is also observed. In the crystal, molecules are linked by pairs of N—H...N hydrogen bonds into inversion dimers. The crystal packing also features C—H...π interactions.

scholarly journals 3-(2-Hydroxy-4-methoxyphenyl)-N-(2-methoxyphenyl)-5-(naphthalen-1-yl)-4,5-dihydro-1H-pyrazole-1-carbothioamide

IUCrData ◽  
2017 ◽  
Vol 2 (5) ◽  
Author(s):  
Seunghyun Ahn ◽  
Yoongho Lim ◽  
Jiha Sung ◽  
Dongsoo Koh
Keyword(s):  
Hydrogen Bond ◽  
Methoxy Group ◽  
Ring System ◽  
Dihedral Angles ◽  
Naphthalene Ring ◽  
Benzene Rings ◽  
Pyrazoline Ring ◽  
Title Molecule ◽  
Phenol Ring ◽  
Ring Motif

In the title molecule, C28H25N3O3S, the dihedral angles formed by the naphthalene ring system and the benzene rings are 73.03 (13) and 74.04 (11)°. The benzene rings attached to the central pyrazoline ring are almost coplanar, as indicated by the dihedral angle of 2.22 (10)° between them. The C atom of the methoxy group of the phenol ring is essentially coplanar with the ring [C—C—O—C = −0.3 (3)°], whereas the C atom of the methoxy group of the thioamide benzene ring is slightly twisted [C—C—O—C = 5.4 (3)°]. An intramolecular O—H...N hydrogen bond generates anS(6) ring motif. In the crystal, pairs of very weak C—H...S interactions form inversion dimers with anR22(18) motif.

scholarly journals 2-[(4,6-Diaminopyrimidin-2-yl)sulfanyl]-N-(4-methoxyphenyl)acetamide

IUCrData ◽  
2018 ◽  
Vol 3 (4) ◽  
Author(s):  
Manisha Choudhury ◽  
Vijayan Viswanathan ◽  
Ajay Kumar Timiri ◽  
Barij Nayan Sinha ◽  
Venkatesan Jayaprakash ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Benzene Ring ◽  
Dihedral Angle ◽  
Title Compound ◽  
Pyrimidine Ring ◽  
Dihedral Angles ◽  
Π Interactions ◽  
Compound C ◽  
Ring Motif

In the title compound, C13H15N5O2S, the acetamide N—C(=O)—C plane makes dihedral angles of 30.51 (11) and 51.93 (11)°, respectively, with the benzene ring and the pyrimidine ring. The dihedral angle between the benzene and pyrimidine rings is 43.40 (6)°. There is an intramolecular N—H...N hydrogen bond with an S(7) ring motif. In the crystal, molecules are linked by pairs of intermolecular N—H...N hydrogen bonds, forming inversion dimers with an R 2 2(8) ring motif. The molecules are further linked by intermolecular N—H...O hydrogen bonds, forming a C(9) chain along [100]. Intermolecular C—H...π and N—H...π interactions are also observed.

scholarly journals 2-[Hydroxy(4-methoxyphenyl)methylidene]indane-1,3-dione

2012 ◽  
Vol 68 (6) ◽  
pp. o1907-o1907
Author(s):  
Jing-Chi Gu ◽  
Bi-Xue Zhu ◽  
Yun-Qian Zhang
Keyword(s):  
Hydrogen Bond ◽  
Benzene Ring ◽  
Dihedral Angle ◽  
Title Compound ◽  
Ring System ◽  
Compound C

In the title compound, C17H12O4, there is an intramolecular O—H...O hydrogen bond. The dihedral angle between the indane ring system [maximun deviation = 0.023 (2) Å] and the benzene ring is 37.42 (9)°.

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