ELECTROPHILIC REACTIONS OF STEROIDAL AND OTHER α-PHENYL DIENES

1966 ◽  
Vol 44 (19) ◽  
pp. 2233-2239
Author(s):  
Maurice Douek ◽  
George Just

3-Phenylcholesta-3,5-diene (I) is shown to undergo electrophilic substitution reactions exclusively at the 6 position with formaldehyde – perchloric acid, acetic anhydride – aluminium chloride, and the Vilsmeier reagent.In the case of formaldehyde, the final product is "dimmer" II. The reaction is specific for formaldehyde and can be used to detect trace amounts of formaldehyde in, for example, commercial acetic acid and acetic anhydride.


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Muhammad Irfan ◽  
Rabia Rehman ◽  
Mohd. R. Razali ◽  
Muhammad Adnan Iqbal ◽  
◽  
...  

AbstractIn wake of emerging applications of organotellurium compounds in biological and material science avenues, the current review describes their key synthetic methodologies while focusing the synthesis of organotellurium compounds through five ligand-to-metal linkages including carbon; carbon-oxygen; carbon-nitrogen; carbon-metal; carbon-sulfur to tellurium. In all of these linkages whether tellurium links with ligands through a complicated or simple pathways, it is often governed through electrophilic substitution reactions. The present study encompasses these major synthetic routes so as to acquire comprehensive understanding of synthetic organotellurium compounds.



1985 ◽  
Vol 21 (7) ◽  
pp. 782-785 ◽  
Author(s):  
E. S. Besidskii ◽  
G. A. Golubeva ◽  
L. A. Sviridova




ChemInform ◽  
1990 ◽  
Vol 21 (21) ◽  
Author(s):  
DZH. ZEGKHUGKH ◽  
SH. A. SAMSONIYA ◽  
D. O. KADZHRISHVILI ◽  
L. M. MAMALADZE




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