scholarly journals Methane formation and water-gas shift reactions over potassium carbonate loaded on coal char at elevated pressure in H2-CO-H2O system.

1985 ◽  
Vol 18 (3) ◽  
pp. 225-230 ◽  
Author(s):  
SHOICHI KIMURA ◽  
SETSUJI TONE ◽  
TSUTAO OTAKE
2008 ◽  
Vol 24 (5) ◽  
pp. 1085-1092 ◽  
Author(s):  
Brad Culbertson ◽  
Raghu Sivaramakrishnan ◽  
Kenneth Brezinsky

2009 ◽  
Vol 42 (3) ◽  
pp. 153-159 ◽  
Author(s):  
Dahlia Diniyati ◽  
Kayoko Morishita ◽  
Liuyun Li ◽  
Takayuki Takarada

1984 ◽  
Vol 17 (5) ◽  
pp. 503-508 ◽  
Author(s):  
TSUTAO OTAKE ◽  
SETSUJI TONE ◽  
SHOICHI KIMURA ◽  
YOICHI HINO

2011 ◽  
Vol 54 (13-15) ◽  
pp. 967-976 ◽  
Author(s):  
P. Piermartini ◽  
T. Schuhmann ◽  
P. Pfeifer ◽  
G. Schaub

1997 ◽  
Author(s):  
Robert Zubrin ◽  
Mitchell Clapp ◽  
Tom Meyer ◽  
Robert Zubrin ◽  
Mitchell Clapp ◽  
...  

2020 ◽  
Author(s):  
Nore Stolte ◽  
Junting Yu ◽  
Zixin Chen ◽  
Dimitri A. Sverjensky ◽  
Ding Pan

The water-gas shift reaction is a key reaction in Fischer-Tropsch-type synthesis, which is widely believed to generate hydrocarbons in the deep carbon cycle, but is little known at extreme pressure-temperature conditions found in Earth’s upper mantle. Here, we performed extensive ab initio molecular dynamics simulations and free energy calculations to study the water-gas shift reaction. We found the direct formation of formic acid out of CO and supercritical water at 10∼13 GPa and 1400 K without any catalyst. Contrary to the common assumption that formic acid or formate is an intermediate product, we found that HCOOH is thermodynamically more stable than the products of the water-gas shift reaction above 3 GPa and at 1000∼1400 K. Our study suggests that the water-gas shift reaction may not happen in Earth’s upper mantle, and formic acid or formate may be an important carbon carrier, participating in many geochemical processes in deep Earth.<br>


2013 ◽  
Vol 33 (9) ◽  
pp. 1572-1577 ◽  
Author(s):  
Yuanzhuo ZHANG ◽  
Ziying YU ◽  
Fumin ZHANG ◽  
Qiang XIAO ◽  
Yijun ZHONG ◽  
...  

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