Fischer carbene complexes. A new tool for heterocyclic synthesis
2002 ◽
Vol 74
(8)
◽
pp. 1317-1325
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Keyword(s):
This short review covers our contribution in the field of the application of group 6 Fischer carbene complexes toward the synthesis of heterocyclic compounds. Alkenyl and alkynyl carbene complexes are suitable partners in [2+2], [3+2], [4+2], and [4+3] cycloaddition reactions. Moreover, chiral alkenyl carbene complexes react in sequential processes involving an initial Michael addition of a ketone lithium enolate to afford lactones with up to five consecutive stereogenic centers. Based on this strategy, we have devised a new method for the enantioselective synthesis of eight-membered carbocycles.
2006 ◽
Vol 71
(26)
◽
pp. 9695-9700
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Keyword(s):
2001 ◽
Vol 7
(20)
◽
pp. 4323-4323
◽
Keyword(s):
1997 ◽
Vol 62
(26)
◽
pp. 9229-9235
◽
Keyword(s):
2001 ◽
Vol 7
(16)
◽
pp. 3533
◽
1999 ◽
Vol 71
(8)
◽
pp. 1453-1461
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Keyword(s):
2021 ◽
Vol 1196
◽
pp. 113121